2021

312.
Y. Xu, H. Yi, and M. Oestreich,
Enantio- and Regioconvergent Synthesis of Allenylsilanes  by Nickel-Catalyzed C(sp²)–C(sp³) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides,
submitted for publication.

311.
N. Kranidiotis-Hisatomi, H. Yi, and M. Oestreich,
Enantio- and Regioconvergent Nickel-Catalyzed C(sp³)–C(sp³) Cross-Coupling of Allylic Electrophiles Steered by a Silyl Group,
submitted for publication.

310.
S. C. Richter and M. Oestreich,
Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C₆F₅)₃-Catalyzed Reduction,
Eur. J. Org. Chem. in revision.

309.
B. M. Gross and M. Oestreich,
The Trityl Cation Embedded into a [7]Helicene-Like Backbone: Preparation and Application as a Lewis Acid Catalyst,
Synthesis 2021, 53, Accepted Manuscript on March 3, 2021 [1]. (Abstract [2])

308.
H. Fang, G. Wang, and M. Oestreich,
Mild Reductive Rearrangement of Oximes and Oxime Ethers to Secondary Amines with Hydrosilanes Catalyzed by B(C₆F₅)₃,
submitted for publication.

307.
E. Romain, K. de la Vega-Hernández, F. Guégan, J. Sanz García, C. Fopp, F. Chemla, F. Ferreira, H. Gerard, O. Jackowski, S. Halbert, M. Oestreich, and A. Perez-Luna,
Development of a Radical Silylzincation of (Het)Aryl-Substituted Alkynes and Computational Insights into the Origin of the Trans-Stereoselectivity,
Adv. Synth. Catal. in revision.

306.
H. F. T. Klare, L. Albers, L. Süsse, S. Keess, T. Müller, and M. Oestreich,
Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts (Review),
Chem. Rev. 2021, 121, accepted for publication.

[3]

© 2021 WILEY-VCH

305.
H. Fang, K. Xie, S. Kemper, and M. Oestreich,
Consecutive β,β’-Selective C(sp³)–H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C₆F₅)₃,
Angew. Chem. Int. Ed. 2021, 60, early view on March 3, 2021 [4]. (Abstract [5])
Selected as a "Hot Paper" by Angewandte Chemie.
(open access)

[6]

© 2021 American Chemical Society

304.
L. Zhang and M. Oestreich,
Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile,
ACS Catal. 2021, 11, 3516-3522 [7]. (Abstract [8])

[9]

© 2021 WILEY-VCH

303.
A. Roy and M. Oestreich,
At Long Last: The Me₃Si Group as a Masked Alcohol (Highlight),
Angew. Chem. 2021, 133, 4456-4458;
Angew. Chem. Int. Ed. 2021, 60, 4408-4410 [10]. (Abstract [11]).

[12]

© 2020 American Chemical Society

302.
Z. Papadopulu and M. Oestreich,
Kinetic Resolution of Neopentylic Secondary Alcohols by Cu–H-Catalyzed Enantioselective Silylation with Hydrosilanes,
Org. Lett. 2021, 23, 438-441 [13]. (Abstract [14])

[15]

© 2020 Royal Society of Chemistry

301.
J.-J. Feng, W. Mao, L. Zhang, and M. Oestreich,
Activation of the Si–B interelement bond related to catalysis (Review),
Chem. Soc. Rev. 2021, 50, 2010-2073 [16]. (Abstract [17])
(open access)

[18]

© 2020 Royal Society of Chemistry

300.
T. He, G. Wang, P.-W. Long, S. Kemper, E. Irran, H. F. T. Klare, and M. Oestreich,
Intramolecular Friedel-Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes,
Chem. Sci. 2021, 12, 569-575 [19]. (Abstract)
Selected for the 2020 Chemical Science HOT Article Collection [20]
(open access)

[21]

© 2020 WILEY-VCH

299.
J. Seliger and M. Oestreich,
Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition-Metal Catalysts,
Angew. Chem. 2021, 133, 251-255;
Angew. Chem. Int. Ed. 2021, 60, 247-251 [22]. (Abstract [23])
Selected as a "Hot Paper" by Angewandte Chemie.
(open access)

2020

[24]

© 2020 American Chemical Society

298.
M. Oberling, E. Irran, Y. Ohki, H. F. T. Klare, and M. Oestreich,
Cationic Ru–Se Complexes for Cooperative Si–H Bond Activation,
Organometallics 2020, 39, 4747-4753 [25]. (Abstract [26])

[27]

© 2020 Royal Society of Chemistry

297.
H. Fang and M. Oestreich,
Defunctionalisation catalysed by boron Lewis acids (Perspective),
Chem. Sci. 2020, 11, 12604-12615 [28]. (Abstract [29])
Part of the themed collection Celebrating 10 years of Chemical Science [30]
(open access)

[31]

© 2020 American Chemical Society

296.
W. Mao and M. Oestreich,
Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors,
Org. Lett. 2020, 22, 8096-8100 [32]. (Abstract [33])

[34]

© 2020 WILEY-VCH

295.
W. Chen, H. Fang, K. Xie, and M. Oestreich,
The Cyclohexa-2,5-dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate,
Chem. Eur. J. 2020, 26, 15126-15129 [35]. (Abstract [36])
(open access)

[37]

© 2020 American Chemical Society

294.
P.-W. Long, T. He, and M. Oestreich,
B(C₆F₅)₃-Catalyzed Hydrosilylation of Vinylcyclopropanes,
Org. Lett. 2020, 22, 7383-7386 [38]. (Abstract [39])

[40]

© 2020 American Chemical Society

293.
W. Xue and M. Oestreich,
Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates (Outlook),
ACS Cent. Sci. 2020, 6, 1070-1081 [41]. (Abstract [42])
ACS AuthorChoice (open access)

[43]

© 2020 WILEY-VCH

292.
C. Chauvier, L. Finck, E. Irran, and M. Oestreich,
Autocatalytic Carbonyl Arylation through In-Situ Release of Aryl Nucleophiles from N-Aryl-N’-Silyldiazenes,
Angew. Chem. 2020, 132, 12436-12440;
Angew. Chem. Int. Ed. 2020, 59, 12337-12341 [44]. (Abstract [45])
(open access)

[46]

© 2020 WILEY-VCH

291.
T. He, G. Wang, V. Bonetti, H. F. T. Klare, and M. Oestreich,
Silylium-Ion-Promoted (5+1) Cycloaddition of Aryl-Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration,
Angew. Chem. 2020, 132, 12284-12289;
Angew. Chem. Int. Ed. 2020, 59, 12186-12191 [47]. (Abstract [48])
(open access)

[49]

© 2020 American Chemical Society

290.
M. Cui and M. Oestreich,
Copper-Catalyzed Enantioselective and Exo-Selective Addition of Silicon Nucleophiles to 7-Oxa- and 7-Azabenzonorbornadiene Derivatives,
Org. Lett. 2020, 22, 3684-3687 [50]. (Abstract [51])

[52]

© 2020 WILEY-VCH

289.
H. Fang and M. Oestreich,
Reductive Deamination with Hydrosilanes Catalyzed by B(C₆F₅)₃,
Angew. Chem. 2020, 132, 11491-11495;
Angew. Chem. Int. Ed. 2020, 59, 11394-11398 [53]. (Abstract [54])
(open access)
Highlighted in SYNFACTS 2020, 16, 837 [55].

[56]

© 2020 WILEY-VCH

288.
Q. Wu, A. Roy, G. Wang, E. Irran, H. F. T. Klare, and M. Oestreich,
Synthesis of a Counteranion-Stabilized Bis(silylium) Ion,
Angew. Chem. 2020, 132, 10609-10613;
Angew. Chem. Int. Ed. 2020, 59, 10523-10526 [57]. (Abstract [58])
Highlighted as a "Very Important Paper (VIP)" by Angewandte Chemie.
(open access)

[59]

© 2020 American Chemical Society

287.
A. Roy, V. Bonetti, G. Wang, Q. Wu, H. F. T. Klare, and M. Oestreich,
Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes,
Org. Lett. 2020, 22, 1213-1216 [60]. (Abstract [61])

[62]

© 2020 WILEY-VCH

286.
D. Janssen-Müller and M. Oestreich, 
Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C-F Coupling of Aryl Boronic Esters (Highlight),
Angew. Chem. 2020, 132, 8404-8406;
Angew. Chem. Int. Ed. 2020, 59, 8328-8330 [63]. (Abstract [64])

[65]

© 2020 American Chemical Society

285.
A.-C. Schulz, S. Frielingsdorf, P. Pommerening, L. Lauterbach, G. Bistoni, F. Neese, M. Oestreich, and O. Lenz,
Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O₂-Tolerant [NiFe] Hydrogenase,
J. Am. Chem. Soc. 2020, 142, 1457-1464 [66]. (Abstract [67])

[68]

© 2019 WILEY-VCH

284.
J. Scharfbier, B. M. Gross, and M. Oestreich,
Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates,
Angew. Chem. 2020, 132, 1593-1596;
Angew. Chem. Int. Ed. 2020, 59, 1577-1580 [69]. (Abstract [70])
(open access)

[71]

© 2020 Springer Nature Limited

283.
J. C. L. Walker, H. F. T. Klare, and M. Oestreich,
Cationic silicon Lewis acids in catalysis (Perspective),
Nat. Rev. Chem. 2020, 4, 54-62 [72]. (Abstract [73])
Commentary: Nat. Rev. Chem. 2020, 4, 4-5 [74].

[75]

© 2019 Elsevier

282.
S. C. Richter and M. Oestreich,
Emerging Strategies for C–H Silylation (Review),
Trends Chem. 2020, 2, 13-27 [76]. (Abstract [77])

2019

[78]

© 2019 American Chemical Society

281.
C. Chauvier, L. Finck, S. Hecht, and M. Oestreich,
General Synthesis and Optical Properties of N-Aryl-N'-Silyldiazenes,
Organometallics 2019, 38, 4679-4686 [79]. (Abstract [80])

[81]

© 2019 Georg Thieme Verlag

280.
J. C. L. Walker and M. Oestreich,
Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates (Account),
Synlett 2019, 30, 2216-2232 [82]. (Abstract [83])

[84]

© 2019 WILEY-VCH

279.
P. Pommerening and M. Oestreich,
Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups,
Eur. J. Org. Chem. 2019, 7240-7246 [85]. (Abstract [86])
(open access)

[87]

© 2019 American Chemical Society

278.
J. Fuchs, E. Irran, P. Hrobárik, H. F. T. Klare, and M. Oestreich,
Si-H Bond Activation with Bullock's Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand,
J. Am. Chem. Soc. 2019, 141, 18845-18850 [88]. (Abstract [89])

[90]

© 2019 WILEY-VCH

277.
Q. Wu, A. Roy, E. Irran, Z.-W. Qu, S. Grimme, H. F. T. Klare, and M. Oestreich,
Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions,
Angew. Chem. 2019, 131, 17468-17472;
Angew. Chem. Int. Ed. 2019, 58, 17307-17311 [91]. (Abstract [92])
Highlighted as a "Very Important Paper (VIP)" by Angewandte Chemie.
(open access)
Highlighted in SYNFACTS 2019, 15, 1427 [93].
Highlighted in Nachr. Chem. 2021, 69, 38-68 [94].

[95]

© 2019 Royal Society of Chemistry

276.
T. Kaicharla, B. M. Zimmermann, M. Oestreich, and J. F. Teichert,
Using alcohols as simple H₂-equivalents for copper-catalysed transfer hydrogenations,
Chem. Commun. 2019, 55, 13410-13413 [96]. (Abstract [97])
Published as a preprint: ChemRxiv 2019, DOI: 10.26434/chemrxiv.9731279.v1 [98].
Highlighted in ChemistryViews Magazine [99].

[100]

© 2019 WILEY-VCH

275.
L. Zhang and M. Oestreich,
Copper-Catalyzed Enantio- and Diastereoselective Addition of Silicon Nucleophiles to 3,3-Disubstituted Cyclopropenes,
Chem. Eur. J. 2019, 25, 14304-14307 [101]. (Abstract [102])
(open access)

[103]

© 2019 WILEY-VCH

274.
T. Hiyama and M. Oestreich (Editors),
Organosilicon Chemistry – Novel Approaches and Reactions [104], Wiley-VCH, Weinheim, 2019 (568 pages, Hardcover).
ISBN: 978-3-527-34453-6.
Buchbesprechung: Nachr. Chem. 2020, 68, 83.

[105]

© 2019 WILEY-VCH

273.
P. Shaykhutdinova, S. Keess, and M. Oestreich,
Cationic Silicon-Based Lewis Acids in Catalysis [106],
in Organosilicon Chemistry – Novel Approaches and Reactions [107] (Eds.: T. Hiyama, M. Oestreich), Wiley-VCH, Weinheim, 2019, 131-170. (Abstract [108])

[109]

© 2019 WILEY-VCH

272.
F. Forster and M. Oestreich,
Metal-Ligand Cooperative Si–H Bond Activation [110],
in Organosilicon Chemistry – Novel Approaches and Reactions [111] (Eds.: T. Hiyama, M. Oestreich), Wiley-VCH, Weinheim, 2019, 115-130. (Abstract [112])

[113]

© 2019 WILEY-VCH

271.
J. C. L. Walker and M. Oestreich,
Lewis Acid-Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers,
Angew. Chem. 2019, 131, 15530-15534;
Angew. Chem. Int. Ed. 2019, 58, 15386-15389 [114]. (Abstract [115])
(open access)
Highlight in SYNFACTS 2019, 15, 1428 [116] as Synfact of the Month!

[117]

© 2019 Royal Society of Chemistry

270.
J.-J. Feng, Y. Xu, and M. Oestreich,
Ligand-Controlled Diastereodivergent, Enantio- and Regioselective Copper-Catalyzed Hydroxyalkylboration of 1,3-Dienes with Ketones,
Chem. Sci. 2019, 10, 9679-9683 [118]. (Abstract)
Selected for the 2019 Chemical Science HOT Article Collection
[119]Part of the 2019 ChemSci Pick of the Week Collection [120]
(open access)
Highlighted in Nat. Catal. 2019, 2, 833 [121].
Highlighted in SYNFACTS 2019, 15, 1402 [122].

[123]

© 2019 AAAS

269.
Q. Wu, E. Irran, R. Müller, M. Kaupp, H. F. T. Klare, and M. Oestreich,
Characterization of hydrogen-substituted silylium ions in the condensed phase,
Science 2019, 365, 168-172 [124]. (Abstract [125])
Highlighted in Nachr. Chem. 2019, 67, 47 [126].
Highlighted in Nachr. Chem. 2020, 68, 50-64 [127].

[128]

© 2019 WILEY-VCH

268.
W. Mao, W. Xue, E. Irran, and M. Oestreich,
Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups,
Angew. Chem. 2019, 131, 10833-10836;
Angew. Chem. Int. Ed. 2019, 58, 10723-10726 [129]. (Abstract [130])
Selected as a "Hot Paper" by Angewandte Chemie.
(open access)
Highlighted in SYNFACTS 2019, 15, 1024 [131].

[132]

© 2019 WILEY-VCH

267.
J. Seliger and M. Oestreich,
Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups (Minireview),
[OMCOS 20 Special Collection [133]]
Chem. Eur. J. 2019, 25, 9358-9365 [134]. (Abstract [135])

[136]

© 2019 WILEY-VCH

266.
S. C. Richter and M. Oestreich,
Bioinspired Metal-Free Formal Decarbonylation of α-Branched Aliphatic Aldehydes at Ambient Temperature,
Chem. Eur. J. 2019, 25, 8508-8512 [137]. (Abstract [138])

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© 2019 American Chemical Society

265.
W. Chen and M. Oestreich,
Metal-Free Transfer Hydrobromination of C–C Triple Bonds,
Org. Lett. 2019, 21, 4531-4534 [140]. (Abstract [141])

[142]

© 2019 WILEY-VCH

264.
J.-J. Feng and M. Oestreich,
Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation,
Angew. Chem. 2019, 131, 8295-8299;
Angew. Chem. Int. Ed. 2019, 58, 8211-8215 [143]. (Abstract [144])
Highlighted in SYNFACTS 2019, 15, 889 [145].

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© 2019 WILEY-VCH

263.
H. Yi and M. Oestreich,
Regiodivergent and Stereospecific Aziridine Opening by Copper-Catalyzed Addition of Silicon Grignard Reagents,
Chem. Eur. J. 2019, 25, 6505-6507 [147]. (Abstract [148])
Selected as a "Hot Paper" by Chemistry - A European Journal.

[149]

© 2019 WILEY-VCH

262.
W. Xue, W. Mao, L. Zhang, and M. Oestreich,
Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp³)–Ge Cross-Coupling with Alkyl Electrophiles,
Angew. Chem. 2019, 131, 6506-6509;
Angew. Chem. Int. Ed. 2019, 58, 6440-6443 [150]. (Abstract [151])

[152]

© 2019 Georg Thieme Verlag

261.
P. Shaykhutdinova and M. Oestreich,
Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones,
Synthesis 2019, 51, 2221-2229 [153]. (Abstract [154])

[155]

© 2019 WILEY-VCH

260.
P. Orecchia, W. Yuan, and M. Oestreich,
Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids,
Angew. Chem. 2019, 131, 3617-3621;
Angew. Chem. Int. Ed. 2019, 58, 3579-3583 [156]. (Abstract [157])

[158]

© 2019 WILEY-VCH

259.
H. Yi, W. Mao, and M. Oestreich,
Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp³)–C(sp³) Cross-Coupling,
Angew. Chem. 2019, 131, 3613-3616;
Angew. Chem. Int. Ed. 2019, 58, 3575-3578 [159]. (Abstract [160])
Highlighted in SYNFACTS 2019, 15, 506 [161].

[162]

© 2019 American Chemical Society

258.
L. Süsse, J. H. W. LaFortune, D. W. Stephan, and M. Oestreich,
Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones,
Organometallics 2019, 38, 712-721 [163]. (Abstract [164])

[165]

© 2019 WILEY-VCH

257.
J. Seliger, X. Dong, and M. Oestreich,
Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu–H-Catalyzed Si–O Coupling,
Angew. Chem. 2019, 131, 1991-1996;
Angew. Chem. Int. Ed. 2019, 58, 1970-1974 [166]. (Abstract [167])

[168]

© 2018 American Chemical Society

256.
W. Chen, J. C. L. Walker, and M. Oestreich,
Metal-Free Transfer Hydroiodination of C‒C Multiple Bonds,
J. Am. Chem. Soc. 2019, 141, 1135-1140 [169]. (Abstract [170])
Highlighted in SYNFACTS 2019, 15, 297 [171].

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© 2018 American Chemical Society

255.
S. Bähr, W. Xue, and M. Oestreich,
C(sp³)–Si Cross-Coupling (Perspective),
ACS Catal. 2019, 9, 16-24 [173]. (Abstract [174])

[175]

© 2018 Georg Thieme Verlag

254.
W. Xue and M. Oestreich,
Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution (Feature Article),
Synthesis 2019, 51, 233-239 [176]. (Abstract [177])
Part of the 50 Years SYNTHESIS -- Golden Anniversary Issue
(open access)

2018

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© 2018 American Chemical Society

253.
L. Zhang and M. Oestreich,
Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles,
Org. Lett. 2018, 20, 8061-8063 [179]. (Abstract [180])

[181]

© 2018 WILEY-VCH

252.
W. Yuan, P. Orecchia, and M. Oestreich,
Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes,
Chem. Eur. J. 2018, 24, 19175-19178 [182]. (Abstract [183])
Selected as a "Hot Paper" by Chemistry - A European Journal.

[184]

© 2018 American Chemical Society

251.
P. Shaykhutdinova and M. Oestreich,
Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels-Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts,
Org. Lett. 2018, 20, 7029-7033 [185]. (Abstract [186])

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250.
J. C. L. Walker and M. Oestreich,
Regioselective Transfer Hydrodeuteration of Alkenes with an HD Surrogate Using B(C₆F₅)₃ Catalysis,
Org. Lett. 2018, 20, 6411-6414 [188]. (Abstract [189])

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249.
A. Merk, H. Großekappenberg, M. Schmidtmann, M.-P. Luecke, C. Lorent, M. Driess, M. Oestreich, H. F. T. Klare, and T. Müller,
Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs,
Angew. Chem. 2018, 130, 15487-15492;
Angew. Chem. Int. Ed. 2018, 57, 15267-15271 [191]. (Abstract [192])
Highlighted in Nat. Rev. Chem. 2018, 2, 255 [193].
Highlighted in Nachr. Chem. 2020, 68, 50-64 [194].

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© 2018 American Chemical Society

248.
M. Vogler, L. Süsse, J. H. W. LaFortune, D. W. Stephan, and M. Oestreich,
Electrophilic Phosphonium Cations as Lewis-Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations,
Organometallics 2018, 37, 3303-3313 [196]. (Abstract [197])

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© 2018 American Chemical Society

247.
H. Hazrati and M. Oestreich,
Copper-Catalyzed Double C(sp³)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism,
Org. Lett. 2018, 20, 5367-5369 [199]. (Abstract [200])

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246.
W. Xue, R. Shishido, and M. Oestreich,
Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cobalt-Catalyzed Radical C(sp³)–Si Cross-Coupling Reactions,
Angew. Chem. 2018, 130, 12318-12322;
Angew. Chem. Int. Ed. 2018, 57, 12141-12145 [202]. (Abstract [203])
Highlighted as a "Very Important Paper (VIP)" by Angewandte Chemie.
Highlighted in SYNFACTS 2018, 14, 1174 [204].

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© 2018 Swiss Chemical Society

245.
F. Forster and M. Oestreich,
Bioinspired Catalytic Generation of Main-Group Electrophiles by Cooperative Bond Activation (Account),
CHIMIA 2018, 72, 584-588 [206].

[207]

© 2018 American Chemical Society

244.
F. Forster, V. M. Rendón López, and M. Oestreich,
Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation,
Organometallics 2018, 37, 2656-2659 [208]. (Abstract [209])

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243.
L. Süsse, M. Vogler, M. Mewald, B. Kemper, E. Irran, and M. Oestreich,
Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral, C₆F₅-Substituted Boron Lewis Acid,
Angew. Chem. 2018, 130, 11612-11615;
Angew. Chem. Int. Ed. 2018, 57, 11441-11444 [211]. (Abstract [212])

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242.
X. Dong, Y. Kita, and M. Oestreich,
Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu–H-Catalyzed Si–O Coupling,
Angew. Chem. 2018, 130, 10888-10891;
Angew. Chem. Int. Ed. 2018, 57, 10728-10731 [214]. (Abstract [215])
Selected as a "Hot Paper" by Angewandte Chemie.
Featured on the Inside Back Cover of Angewandte Chemie [216].

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241.
J.-J. Feng and M. Oestreich,
Copper-Catalyzed Silylation of C(sp³)-H Bonds Adjacent to Amide Nitrogen Atoms,
Org. Lett. 2018, 20, 4273-4276 [218]. (Abstract [219])

[220]

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240.
Q. Wu, Z.-W. Qu, L. Omann, E. Irran, H. F. T. Klare, and M. Oestreich,
Cleavage of Unactivated Si‒C(sp³) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions,
Angew. Chem. 2018, 130, 9317-9320;
Angew. Chem. Int. Ed. 2018, 57, 9176-9179 [221]. (Abstract [222])
Highlighted in Nachr. Chem. 2018, 66, 942 [223].

[224]

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239.
L. Omann, B. Pudasaini, E. Irran, H. F. T. Klare, M.-H. Baik, and M. Oestreich,
Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion,
Chem. Sci. 2018, 9, 5600-5607 [225]. (Abstract)
Selected for the 2018 Chemical Science HOT Article Collection [226]
(open access)

[227]

© 2018 WILEY-VCH

238.
L. Omann, Z.-W. Qu, E. Irran, H. F. T. Klare, S. Grimme, and M. Oestreich,
Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide,
Angew. Chem. 2018, 130, 8433-8437;
Angew. Chem. Int. Ed. 2018, 57, 8301-8305 [228]. (Abstract [229])

[230]

© 2018 WILEY-VCH

237.
P. Shaykhutdinova, S. Kemper, and M. Oestreich,
Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs: Improved Enantioselectivity in the Diels-Alder Reaction of Cyclohexa-1,3-diene and Chalcone Derivatives,
Eur. J. Org. Chem. 2018, 2896-2901 [231]. (Abstract [232])
Part of A Dutch-German Initiative Virtual Issue [233].
Part of Board Member Virtual Issue [234].
(open access)

[235]

© 2018 Elsevier

236.
W. Yuan, P. Smirnov, and M. Oestreich,
Custom Hydrosilane Synthesis Based on Monosilane,
Chem 2018, 4, 1443-1450 [236]. (Abstract [237])

[238]

© 2018 WILEY-VCH

235.
P. Pommerening, T. Stahl, and M. Oestreich,
Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self Reaction Promoted by a Tethered Ru-S Complex,
Eur. J. Org. Chem. 2018, 2290-2293. [239] (Abstract [240])

[241]

© 2018 WILEY-VCH

234.
S. Bähr and M. Oestreich,
A Neutral Ru(II) Hydride Complex for the Regio- and Chemoselective Reduction of N-Silylpyridinium Ions,
Chem. Eur. J. 2018, 24, 5613-5622 [242]. (Abstract [243])

[244]

© 2018 IUPAC & De Gruyter

233.
S. Bähr and M. Oestreich,
The Electrophilic Aromatic Substitution Approach to C-H Silylation and C-H Borylation
(IMEBORON XVI Conference Issue [245]),
Pure Appl. Chem. 2018, 90, 723-731 [246]. (Abstract [247])

[248]

© 2018 American Chemical Society

232.
F. Forster, V. M. Rendón López, and M. Oestreich,
Catalytic Dehydrogenative Stannylation of C(sp)-H Bonds Involving Cooperative Sn-H Bond Activation of Hydrostannanes,
J. Am. Chem. Soc. 2018, 140, 1259-1262 [249]. (Abstract [250])

2017

[251]

© 2017 American Chemical Society

231.
J. Scharfbier, H. Hazrati, E. Irran, and M. Oestreich,
Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration,
Org. Lett. 2017, 19, 6562-6565 [252]. (Abstract [253])
Highlighted in SYNFACTS 2018, 14, 165 [254].

[255]

© 2017 American Chemical Society

230.
J. Fuchs, H. F. T. Klare, and M. Oestreich,
Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst,
ACS Catal. 2017, 7, 8338-8342 [256]. (Abstract [257])

[258]

© 2017 American Chemical Society

229.
F. Forster, T. T. Metsänen, E. Irran, P. Hrobárik, and M. Oestreich,
Cooperative Al-H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel-Crafts Alkylation,
J. Am. Chem. Soc. 2017, 139, 16334-16342 [259]. (Abstract [260])
Featured on the Front Cover of JACS [261].

[262]

© 2017 Royal Society of Chemistry

228.
M.-P. Luecke, D. Porwal, A. Kostenko, Y.-P. Zhou, S. Yao, M. Keck, C. Limberg, M. Oestreich, and M. Driess,
Bis(silylenyl)-substituted ferrocene-stabilized η⁶-arene iron(0) complexes: synthesis, structure and catalytic application,
Dalton Trans. 2017, 46, 16412-16418 [263]. (Abstract)
Featured on the Front Cover of Dalton Transactions [264].

[265]

© 2017 American Chemical Society

227.
S. Bähr, H. Ogasawara, S. Yamaguchi, and M. Oestreich,
An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Related Systems,
Organometallics 2017, 36, 4013-4019 [266]. (Abstract [267])

[268]

© 2017 Georg Thieme Verlag

226.
S. Wübbolt and M. Oestreich,
Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si-H Bond Activation
(SYNLETT Cluster on Silicon in Synthesis and Catalysis [269]),
Synlett 2017, 28, 2411-2414 [270]. (Abstract [271])

Preface by M. Oestreich,
Synlett 2017, 28, 2394-2395 [272]. (Abstract [273])

[274]

© 2017 Royal Society of Chemistry

225.
W. Yuan, P. Orecchia, and M. Oestreich,
Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C₆F₅)₃-catalysed transfer processes,
Chem. Commun. 2017, 53, 10390-10393 [275]. (Abstract)

[276]

© 2017 WILEY-VCH

224.
W. Xue and M. Oestreich,
Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxylic Acid Derivatives,
Angew. Chem. 2017, 129, 11808-11811;
Angew. Chem. Int. Ed. 2017, 56, 11649-11652 [277]. (Abstract [278])

[279]

© 2017 Georg Thieme Verlag

223.
D. Porwal and M. Oestreich,
B(C₆F₅)₃-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes,
Synthesis 2017, 49, 4698-4702 [280]. (Abstract [281])

[282]

© John Wiley & Sons, Ltd

222.
S. Keess and M. Oestreich,
Tri(cyclohexa-2,5-dien-1-yl)silane,
in Electronic Encyclopedia of Reagents for Organic Synthesis [283] (Eds.: D. Crich, P. L. Fuchs, A. B. Charette, and T. Rovis), Wiley, Chichester, 2017.
(Abstract [284])

[285]

© 2017 American Chemical Society

221.
Q. Yin, Y. Soltani, R. L. Melen, and M. Oestreich,
BAr^F₃-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base,
Organometallics 2017, 36, 2381-2384 [286]. (Abstract [287])

[288]

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220.
S. Keess and M. Oestreich,
Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes (Minireview),
Chem. Sci. 2017, 8, 4688-4695 [289]. (Abstract)
(open access)

[290]

© 2017 WILEY-VCH

219.
Q. Yin and M. Oestreich,
Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at Room Temperature (Highlight),
Angew. Chem. 2017, 129, 7824-7826;
Angew. Chem. Int. Ed. 2017, 56, 7716-7718 [291]. (Abstract [292])

[293]

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218.
X. Dong, A. Weickgenannt, and M. Oestreich,
Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes,
Nat. Commun. 2017, 8, 15547 [294]. (Abstract)
(open access)

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© 2017 American Chemical Society

217.
W.-B. Liu, D. P. Schuman, Y.-F. Yang, A. A. Toutov, Y. Liang, H. F. T. Klare, N. Nesnas, M. Oestreich, D. G. Blackmond, S. C. Virgil, S. Banerjee, R. N. Zare, R. H. Grubbs, K. N. Houk, and B. M. Stoltz,
Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study,
J. Am. Chem. Soc. 2017, 139, 6867-6879 [296]. (Abstract [297])

[298]

© 2017 American Chemical Society

216.
L. Omann, C. D. F. Königs, H. F. T. Klare, and M. Oestreich,
Cooperative Catalysis at Metal–Sulfur Bonds (Account),
Acc. Chem. Res. 2017, 50, 1258-1269 [299]. (Abstract [300])

[301]

© 2017 Elsevier

215.
L.-Y. Jiao and M. Oestreich,
C-H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3) [302],
in Strategies for Palladium-Catalyzed Non-Directed and Directed C-H Bond Functionalization [303] (Eds.: A. R. Kapdi, D. Maiti), Elsevier, Oxford, 2017, 205-232. (Abstract)

[304]

© 2017 WILEY-VCH

214.
P. Pommerening, J. Mohr, J. Friebel, and M. Oestreich,
Synthesis of a Chiral Borate Counteranion, its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis,
Eur. J. Org. Chem. 2017, 2312-2316 [305]. (Abstract [306])

[307]

© 2017 WILEY-VCH

213.
S. Wübbolt, M. S. Maji, E. Irran, and M. Oestreich,
A Tethered Ru–S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si‒H Bond Activation: Application to Enantioselective Imine Reduction,
[Collaborative Research Center (SFB 858) on Cooperative Effects [308]]
Chem. Eur. J. 2017, 23, 6213-6219 [309]. (Abstract [310])

[311]

© 2016 WILEY-VCH

212.
S. Keess and M. Oestreich,
3-tert-Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6F5)3-Catalyzed Transfer Hydro-tert-Butylation of Alkenes,
[Collaborative Research Center (SFB 858) on Cooperative Effects [312]]
Chem. Eur. J. 2017, 23, 5925-5928 [313]. (Abstract [314])

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211.
L. B. Delvos and M. Oestreich,
Silylboron Reagents (Volume 4, Product Class 7, Section 4.4.7),
in Science of Synthesis Knowledge Updates 2017/1 [316] (Ed.: M. Oestreich), Thieme, Stuttgart, 2017, 65-176. (Abstract [317])

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210.
S. Keess and M. Oestreich,
Access to Fully Alkylated Germanes by B(C₆F₅)₃-Catalyzed Transfer Hydrogermylation of Alkenes,
Org. Lett. 2017, 19, 1898-1901 [319]. (Abstract [320])

[321]

© 2017 WILEY-VCH

209.
Q. Yin, H. F. T. Klare, and M. Oestreich,
Catalytic Friedel–Crafts C–H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes,
Angew. Chem. 2017, 129, 3766-3771;
Angew. Chem. Int. Ed. 2017, 56, 3712-3717 [322]. (Abstract [323])
Highlighted in SYNFACTS 2017, 13, 529 [324].

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208.
I. Chatterjee, D. Porwal, and M. Oestreich,
B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes,
Angew. Chem. 2017, 129, 3438-3441;
Angew. Chem. Int. Ed. 2017, 56, 3389-3391 [326]. (Abstract [327])

[328]

© 2017 American Chemical Society

207.
S. Bähr and M. Oestreich,
Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C=N and C=O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand,
Organometallics 2017, 36, 935-943 [329]. (Abstract [330])

[331]

© 2016 American Chemical Society

206.
L. Omann and M. Oestreich,
Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation with Dihydrosilanes,
Organometallics 2017, 36, 767-776 [332]. (Abstract [333])
Featured on the Cover of Organometallics [334].

[335]

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205.
C. Fopp, K. Isaac, E. Romain, F. Chemla, F. Ferreira, O. Jackowski, M. Oestreich, and A. Perez-Luna,
Stereodivergent Synthesis of beta-Heteroatom-Substituted Vinylsilanes by Sequential Silylzincation-Cu(I)-Mediated Electrophilic Substitution (Feature Article),
Synthesis 2017, 49, 724-735 [336]. (Abstract [337])

[338]

© 2016 WILEY-VCH

204.
S. Bähr and M. Oestreich,
Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C-H Silylation (Minireview),
Angew. Chem. 2017, 129, 52-59;
Angew. Chem. Int. Ed. 2017, 56, 52-59 [339]. (Abstract [340])

2016

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© 2016 AAAS

203.
H. F. T. Klare and M. Oestreich,
Teaching nature the unnatural (Perspective),
Science 2016, 354, 970 [342]. (Abstract [343])

[344]

© 2016 American Chemical Society

202.
W. Xue, Z.-W. Qu. S. Grimme, and M. Oestreich,
Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization,
J. Am. Chem. Soc. 2016, 138, 14222-14225 [345]. (Abstract [346])

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201.
J. Mohr and M. Oestreich,
Balancing C=C Functionalization and C=O Reduction in Cu-H Catalysis (Highlight),
Angew. Chem. 2016, 128, 12330-12332;
Angew. Chem. Int. Ed. 2016, 55, 12148-12149 [348]. (Abstract [349])

[350]

© 2016 American Chemical Society

200.
P. Shaykhutdinova and M. Oestreich,
Enantioselective Diels−Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed by Intramolecular Silicon–Sulfur Lewis Pairs as Chiral Lewis Acids,
Organometallics 2016, 35, 2768-2771 [351]. (Abstract [352])

[353]

© 2016 WILEY-VCH

199.
Q. Yin, S. Kemper, H. F. T. Klare, and M. Oestreich,
Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6F5)3 Cannot Do!,
Chem. Eur. J. 2016, 22, 13840-13844 [354]. (Abstract [355])

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198.
P. Smirnov and M. Oestreich,
Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes,
Organometallics 2016, 35, 2433-2434 [357]. (Abstract [358])

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© 2016 American Chemical Society

197.
Q.-A. Chen, H. F. T. Klare, and M. Oestreich,
Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation,
J. Am. Chem. Soc. 2016, 138, 7868-7871 [360]. (Abstract [361])
ACS AuthorChoice (open access)

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196.
D. Porwal and M. Oestreich,
B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes,
Eur. J. Org. Chem. 2016, 3307-3309 [363]. (Abstract [364])

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195.
I. Chatterjee and M. Oestreich,
Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates,
Org. Lett. 2016, 18, 2463-2466 [366]. (Abstract [367])
ACS AuthorChoice (open access)
Highlighted in SYNFACTS 2016, 12, 971 [368].

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194.
L. Süsse, J. Hermeke, and M. Oestreich,
The Asymmetric Piers Hydrosilylation,
J. Am. Chem. Soc. 2016, 138, 6940-6943 [370]. (Abstract [371])
ACS AuthorChoice (open access)
Highlighted in SYNFACTS 2016, 12, 833 [372].

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193.
A. Lefranc, Z.-W. Qu, S. Grimme, and M. Oestreich,
Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru‒S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates,
Chem. Eur. J. 2016, 22, 10009-10016 [374]. (Abstract [375])

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192.
C. Fopp, E. Romain, K. Isaac, F. Chemla, F. Ferreira, O. Jackowski, M. Oestreich, and A. Perez-Luna,
Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes,
Org. Lett. 2016, 18, 2054-2057 [377]. (Abstract [378])
Highlighted in SYNFACTS 2016, 12, 729 [379].

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191.
M. Mehta, I. Garcia de la Arada, M. Perez, D. Porwal, M. Oestreich, and D. W. Stephan,
Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations,
Organometallics 2016, 35, 1030-1035 [381]. (Abstract [382])

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© 2016 American Chemical Society

190.
S. Bähr, A. Simonneau, E. Irran, and M. Oestreich,
An Air-Stable Dimeric Ru-S Complex with an NHC as Ancillary Ligand for Cooperative Si-H Bond Activation,
Organometallics 2016, 35, 925-928 [384]. (Abstract [385])
ACS AuthorChoice (open access) 

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189.
J. Scharfbier and M. Oestreich,
Copper-Catalyzed Si-B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates,
Synlett 2016, 27, 1274-1276 [387]. (Abstract [388])

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© Springer

188.
A. Hensel and M. Oestreich,
Asymmetric Addition of Boron and Silicon Nucleophiles [390],
in Progress in Enantioselective Cu(I)-catalyzed Formation of Stereogenic Centers (Ed.: S. R. Harutyunyan), Springer International Publishing Switzerland,
Top. Organomet. Chem. 2016, 58, 135-167.

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187.
A. Simonneau and M. Oestreich,
3-(Trimethylsilyl)-1,4-cyclohexadiene,
in Electronic Encyclopedia of Reagents for Organic Synthesis [392] (Eds.: D. Crich, P. L. Fuchs, A. B. Charette, and T. Rovis), Wiley, Chichester, 2016. (Abstract [393])

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186.
R. K. Schmidt, H. F. T. Klare, R. Fröhlich, and M. Oestreich,
Planar Chiral, Ferrocene-Stabilized Silicon Cations,
Chem. Eur. J. 2016, 22, 5376-5383 [395]. (Abstract [396])

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185.
Q. Yin, H. F. T. Klare, and M. Oestreich,
Friedel–Crafts-Type Intermolecular C–H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts,
Angew. Chem. 2016, 128, 3256-3260;
Angew. Chem. Int. Ed. 2016, 55, 3204-3207 [398]. (Abstract [399])

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184.
L.-Y. Jiao, A. V. Ferreira, and M. Oestreich,
Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed ortho C-H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
(Special Issue on Catalysis and Transformation of Complex Molecules),
Chem. Asian J. 2016, 11, 367-370 [401]. (Abstract [402])

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183.
M. Oestreich,
Transfer Hydrosilylation (Minireview),
Angew. Chem. 2016, 128, 504-509;
Angew. Chem. Int. Ed. 2016, 55, 494-499 [404]. (Abstract [405])
(open access)

2015

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182.
S. Wübbolt and M. Oestreich,
Catalytic Electrophilic C-H Silylation of Pyridines Enabled by Temporary Dearomatization,
Angew. Chem. 2015, 127, 16103-16106;
Angew. Chem. Int. Ed. 2015, 54, 15876-15879 [407]. (Abstract [408])

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181.
J. Mohr, D. Porwal, I. Chatterjee, and M. Oestreich,
Extending the Scope of the B(C6F5)3-Catalyzed C=N Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones,
Chem. Eur. J. 2015, 21, 17583-17586 [410]. (Abstract [411])

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180.
T. T. Metsänen, D. Gallego, T. Szilvási, M. Driess, and M. Oestreich,
Peripheral mechanism of a carbonyl hydrosilylation catalyzed by an SiNSi iron pincer complex,
Chem. Sci. 2015, 6, 7143-7149 [413]. (Abstract)
(open access)

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179.
T. Fallon and M. Oestreich,
A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
(Special Issue: Chemistry in Germany and Israel),
Angew. Chem. 2015, 127, 12666-12670;
Angew. Chem. Int. Ed. 2015, 54, 12488-12491 [415]. (Abstract [416])
Highlighted as a "Very Important Paper (VIP)" by Angewandte Chemie.
Featured on the Back Cover of Angewandte Chemie [417].

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178.
I. Chatterjee, Z.-W. Qu, S. Grimme, and M. Oestreich,
B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another,
Angew. Chem. 2015, 127, 12326-12330;
Angew. Chem. Int. Ed. 2015, 54, 12158-12162 [419]. (Abstract [420])

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177.
A. Simonneau, T. Biberger, and M. Oestreich,
The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions,
Organometallics 2015, 34, 3927-3929 [422]. (Abstract [423])
ACS AuthorChoice (open access)

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176.
A. Simonneau and M. Oestreich,
Formal SiH4 chemistry using stable and easy-to-handle surrogates,
Nat. Chem. 2015, 7, 816-822 [425]. (Abstract [426])
Highlighted in SYNFACTS 2015, 11, 1158 [427].
Highlighted in Nachr. Chem. 2016, 64, 6.

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175.
L. Omann and M. Oestreich,
A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores,
Angew. Chem. 2015, 127, 10414-10418;
Angew. Chem. Int. Ed. 2015, 54, 10276-10279 [429]. (Abstract [430])

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174.
V. H. G. Rohde, M. F. Müller, and M. Oestreich,
Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels-Alder Reactions,
Organometallics 2015, 34, 3358-3373 [432]. (Abstract [433])
ACS AuthorChoice (open access)

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173.
T. Stahl, P. Hrobárik, C. D. F. Königs, Y. Ohki, K. Tatsumi, S. Kemper, M. Kaupp, H. F. T. Klare, and M. Oestreich,
Mechanism of the cooperative Si–H bond activation at Ru–S bonds,
Chem. Sci. 2015, 6, 4324-4334 [435]. (Abstract)
(open access)

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172.
A. Hensel and M. Oestreich,
Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors,
Chem. Eur. J. 2015, 21, 9062-9065 [437]. (Abstract [438])
Highlighted in SYNFACTS 2015, 11, 829 [439].

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171.
M. Pareek, T. Fallon, and M. Oestreich,
Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki-Miyaura Cross-Coupling,
Org. Lett. 2015, 17, 2082-2085 [441]. (Abstract [442])
ACS AuthorChoice (open access)
Highlighted to SYNFACTS 2015, 11, 855 [443].

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170.
A. Simonneau and M. Oestreich,
Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis (Highlight),
Angew. Chem. 2015, 127, 3626-3628;
Angew. Chem. Int. Ed. 2015, 54, 3556-3558 [445]. (Abstract [446])

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169.
L. B. Delvos and M. Oestreich,
Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution (Feature Article),
Synthesis 2015, 47, 924-933 [448]. (Abstract [449])

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168.
X. Zhou, K. Szeker, L.-Y. Jiao, M. Oestreich, I. A. Mikhailopulo, and P. Neubauer,
Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases,
Adv. Synth. Catal. 2015, 357, 1237-1244 [451]. (Abstract [452])

167.
M. Oestreich and A. Simonneau,
Use of cyclohexa-2,5-dien-1-yl-silanes as precursors for gaseous hydrosilanes,
Eur. Pat. Appl. 2015, EP 2845857 (PCT Int. Appl. WO 2015/036309 A1).

[453]

© 2015 American Chemical Society

166.
S. Keess, A. Simonneau, and M. Oestreich,
Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study,
Organometallics 2015, 34, 790-799 [454]. (Abstract [455])
ACS AuthorChoice (open access)

[456]

© 2015 Royal Society of Chemistry

165.
M. Oestreich, J. Hermeke, and J. Mohr,
A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes (Review),
Chem. Soc. Rev. 2015, 44, 2202-2220 [457]. (Abstract)
(open access)

[458]

© 2014 American Chemical Society

164.
T. T. Metsänen and M. Oestreich,
Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State,
Organometallics 2015, 34, 543-546 [459]. (Abstract [460])
Featured on the Cover of Organometallics [461].

[462]

© 2014 WILEY-VCH

163.
I. Chatterjee and M. Oestreich,
B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source,
Angew. Chem. 2015, 127, 1988-1991;
Angew. Chem. Int. Ed. 2015, 54, 1965-1968 [463]. (Abstract [464])

2014

[465]

© 2014 American Chemical Society

162.
L.-Y. Jiao, P. Smirnov, and M. Oestreich,
Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C-H/C-H Arylation of Indolines at the C-7 Position under Air,
Org. Lett. 2014, 16, 6020-6023 [466]. (Abstract [467])

[468]

© 2014 American Chemical Society

161.
J. Hermeke, M. Mewald, E. Irran, and M. Oestreich,
Chemoselective Tin-Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom,
Organometallics 2014, 33, 5097-5100 [469]. (Abstract [470])

[471]

© 2014 WILEY-VCH

160.
J. Mohr and M. Oestreich,
B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the N-O Bond,
Angew. Chem. 2014, 126, 13494-13497;
Angew. Chem. Int. Ed. 2014, 53, 13278-13281 [472]. (Abstract [473])

[474]

© 2014 WILEY-VCH

159.
E. Romain, C. Fopp, F. Chemla, F. Ferreira, O. Jackowski, M. Oestreich, and A. Perez-Luna,
Trans-Selective Radical Silylzincation of Ynamides,
Angew. Chem. 2014, 126, 11515-11519;
Angew. Chem. Int. Ed. 2014, 53, 11333-11337 [475]. (Abstract [476])
Highlighted in SYNFACTS 2015, 11, 79 [477].

[478]

© Georg Thieme Verlag

158.
L. B. Delvos, A. Hensel, and M. Oestreich,
McQuade's 6-Membered NHC-Copper(I) Complexes for Catalytic Asymmetric Silyl Transfer,
Synthesis 2014, 46, 2957-2964 [479]. (Abstract [480])

[481]

© WILEY-VCH

157.
C. K. Hazra, C. Fopp, and M. Oestreich,
Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds,
Chem. Asian J. 2014, 9, 3005-3010 [482]. (Abstract [483])

[484]

© 2014 American Chemical Society

156.
V. H. G. Rohde, P. Pommerening, H. F. T. Klare, and M. Oestreich,
Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts,
Organometallics 2014, 33, 3618-3628 [485]. (Abstract [486])

[487]

© 2014 American Chemical Society

155.
K. M. Redies, T. Fallon, and M. Oestreich,
En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(α-spirocyclopropyl)silylene,
Organometallics 2014, 33, 3235-3238 [488]. (Abstract [489])

[490]

© 2014 American Chemical Society

154.
T. T. Metsänen, P. Hrobárik, H. F. T. Klare, M. Kaupp, and M. Oestreich,
Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart's Cationic Iridium(III) Pincer Complex,
J. Am. Chem. Soc. 2014, 136, 6912-6915 [491]. (Abstract [492])
Highlighted in ChemCatChem 2014, 6, 2486-2489 [493].

[494]

© 2014 WILEY-VCH

153.
J. Hermeke, H. F. T. Klare, and M. Oestreich,
Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative Si–N Coupling
(ISOS XVII Conference Issue New Frontiers and Challenges in Silicon Chemistry [495]),
Chem. Eur. J. 2014, 20, 9250-9254 [496]. (Abstract [497])

Editorial by M. Driess and M. Oestreich,
Chem. Eur. J. 2014, 20, 9144-9145 [498]. (Abstract [499])

[500]

© 2014 WILEY-VCH

152.
A. Hensel, K. Nagura, L. B. Delvos, and M. Oestreich,
Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst,
Angew. Chem. 2014, 126, 5064-5067;
Angew. Chem. Int. Ed. 2014, 53, 4964-4967 [501]. (Abstract [502])
Highlighted in SYNFACTS 2014, 10, 840 [503].

[504]

© 2014 American Chemical Society

151.
J. Mohr, M. Durmaz, E. Irran, and M. Oestreich,
Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom,
Organometallics 2014, 33, 1108-1111 [505]. (Abstract [506])

[507]

© 2014 WILEY-VCH

150.
S. R. Kandukuri, L.-Y. Jiao, A. B. Machotta, and M. Oestreich,
Diastereotopic Group Selection in Hydroxy-Directed Intramolecular C-H Alkenylation of Indole under Oxidative Palladium(II) Catalysis
(Special Thematic Issue on Directed C-H Functionalization),
Adv. Synth. Catal. 2014, 356, 1597-1609 [508]. (Abstract [509])

[510]

© 2014 Elsevier Ltd.

149.
U. Hennecke, C. Rösner, T. Wald, T. Robert, and M. Oestreich,
Addition Reactions with Formation of Carbon-Halogen Bonds [511],
in Comprehensive Organic Synthesis II (Eds.: G. Molander and P. Knochel), Elsevier, Oxford, 2014, Vol. 7, 638-691 (Abstract [512]).

[513]

© 2014 WILEY-VCH

148.
A. Simonneau, J. Friebel, and M. Oestreich,
Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylation by Using a Me3SiH Surrogate,
Eur. J. Org. Chem. 2014, 2077-2083 [514]. (Abstract [515])

[516]

© 2014 WILEY-VCH

147.
M. Oestreich,
Breaking News on the Enantioselective Intermolecular Heck Reaction (Highlight),
Angew. Chem. 2014, 126, 2314-2317;
Angew. Chem. Int. Ed. 2014, 53, 2282-2285 [517]. (Abstract [518])

[519]

© 2014 John Wiley & Sons, Inc.

146.
A. de Meijere, S. Bräse, and M. Oestreich (Editors),
Metal-Catalyzed Cross-Coupling Reactions and More [520], Wiley-VCH, Weinheim, 2014 (1576 pages, Hardcover).
ISBN: 978-3-527-33154-3.
Book Review: Angew. Chem. 2014, 126, 13215-13216 [521]; Angew. Chem. Int. Ed. 2014, 53, 13001-13002 [522].

[523]

© 2013 American Chemical Society

145.
A. R. Nödling, K. Müther, V. H. G. Rohde, G. Hilt, and M. Oestreich,
Ferrocene-Stabilized Silicon Cations as Catalysts for Diels-Alder Reactions: Attempted Experimental Quantification of Lewis Acidity and ReactIR Kinetic Analysis,
Organometallics 2014, 33, 302-308 [524]. (Abstract [525])

2013

[526]

© 2013 American Chemical Society

144.
L.-Y. Jiao and M. Oestreich,
Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines,
Org. Lett. 2013, 15, 5374-5377 [527]. (Abstract [528])

[529]

© 2013 American Chemical Society

143.
J. Hermeke, M. Mewald, and M. Oestreich,
Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism,
J. Am. Chem. Soc. 2013, 135, 17537-17546 [530]. (Abstract [531])

[532]

© 2013 Teknoscienze S.r.l.

142.
L. B. Delvos and M. Oestreich,
Direct and Indirect Synthesis of alpha-Chiral Allylic Silanes by Asymmetric Allylic Substitution with Silicon and Carbon Nucleophiles,
Chemistry TODAY / Chimica OGGI 2013, 31, 74-77 [533] (September/October issue).

[534]

© 2013 WILEY-VCH

141.
K. Müther, P. Hrobárik, V. Hrobáriková, M. Kaupp, and M. Oestreich,
The Family of Ferrocene-Stabilized Silylium Ions: Synthesis, 29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum-Chemical Analyses,
Chem. Eur. J. 2013, 19, 16579-16594 [535]. (Abstract [536])
Highlighted as a "Very Important Paper (VIP)" by Chemistry - A European Journal.

[537]

© 2013 WILEY-VCH

140.
A. Simonneau and M. Oestreich,
3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes,
Angew. Chem. 2013, 125, 12121-12124;
Angew. Chem. Int. Ed. 2013, 52, 11905-11907 [538]. (Abstract [539])
Highlighted in SYNFACTS 2014, 10, 73 [540].

[541]

© 2013 American Chemical Society

139.
T. Stahl, K. Müther, Y. Ohki, K. Tatsumi, and M. Oestreich,
Catalytic Generation of Borenium Ions by Cooperative B-H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane,
J. Am. Chem. Soc. 2013, 135, 10978-10981 [542]. (Abstract [543])
Highlighted in SYNFACTS 2013, 9, 1216 [544].

[545]

© 2013 WILEY-VCH

138.
C. D. F. Königs, H. F. T. Klare, and M. Oestreich,
Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners,
Angew. Chem. 2013, 125, 10260-10263;
Angew. Chem. Int. Ed. 2013, 52, 10076-10079 [546]. (Abstract [547])
Selected as a "Hot Paper" by Angewandte Chemie.

[548]

© 2013 WILEY-VCH

137.
L.-Y. Jiao and M. Oestreich,
Oxidative Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C-7 Position,
Chem. Eur. J. 2013, 19, 10845-10848 [549]. (Abstract [550])

[551]

© 2013 WILEY-VCH

136.
C. K. Hazra, E. Irran, and M. Oestreich,
Regio- and Diastereoselective, Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by Silicon Nucleophile,
Eur. J. Org. Chem. 2013, 4903-4908 [552]. (Abstract [553])

[554]

© 2013 American Chemical Society

135.
T. Stahl, H. F. T. Klare, and M. Oestreich,
Main-Group Lewis Acids for C–F Bond Activation (Perspective),
ACS Catal. 2013, 3, 1578-1587 [555]. (Abstract [556])
Featured on the Cover of ACS Catalysis [557].

[558]

© 2013 American Chemical Society

134.
K. Müther, J. Mohr, and M. Oestreich,
Silylium Ion Promoted Reduction of Imines with Hydrosilanes
(Special Issue on Applications of Electrophilic Main Group Organometallic Molecules),
Organometallics 2013, 32, 6643-6646 [559]. (Abstract [560])

[561]

© 2013 WILEY-VCH

133.
T. Robert and M. Oestreich,
Si-H Bond Activation: Bridging Lewis Acid Catalysis with Brookhart's Iridium(III) Pincer Complex and B(C6F5)3 (Highlight),
Angew. Chem. 2013, 125, 5324-5326;
Angew. Chem. Int. Ed. 2013, 52, 5216-5218 [562]. (Abstract [563])

[564]

© 2013 WILEY-VCH

132.
L. B. Delvos, D. J. Vyas, and M. Oestreich,
Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation,
Angew. Chem. 2013, 125, 4748-4751;
Angew. Chem. Int. Ed. 2013, 52, 4650-4653 [565]. (Abstract [566])
Highlighted in SYNFACTS 2013, 9, 744 [567].

[568]

© 2013 The Royal Society of Chemistry

131.
C. D. F. Königs, M. F. Müller, N. Aiguabella, H. F. T. Klare, and M. Oestreich,
Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base,
Chem. Commun. 2013, 49, 1506-1508 [569]. (Abstract [570])

[571]

© 2013 American Chemical Society

130.
T. Stahl, H. F. T. Klare, and M. Oestreich,
C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle,
J. Am. Chem. Soc. 2013, 135, 1248-1251 [572]. (Abstract [573])

[574]

© 2013 American Chemical Society

129.
M. Oestreich, E. Hartmann, and M. Mewald,
Activation of the Si-B Interelement Bond: Mechanism, Catalysis, and Synthesis (Review),
Chem. Rev. 2013, 113, 402-441 [575]. (Abstract [576])

2012

[577]

© Verlag der Zeitschrift für Naturforschung

128.
W. Nie, H. F. T. Klare, M. Oestreich, R. Fröhlich, G. Kehr, and G. Erker,
Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
(Special Issue dedicated to Professor Heribert Offermanns),
Z. Naturforsch. 2012, 67b, 987-994 [578]. (Abstract [579])

[580]

© 2012 WILEY-VCH

127.
M. Mewald and M. Oestreich,
Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane,
Chem. Eur. J. 2012, 18, 14079-14084 [581]. (Abstract [582])

[583]

© 2012 American Chemical Society

126.
S. R. Kandukuri and M. Oestreich,
Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides: An Indole-Directed Aromatization,
J. Org. Chem. 2012, 77, 8750-8755 [584]. (Abstract [585])

[586]

© 2012 WILEY-VCH

125.
T. H. Wöste and M. Oestreich,
Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations,
ChemCatChem 2012, 4, 2096-2101 [587]. (Abstract [588])
Highlighted in ChemViews Magazine [589].

[590]

© 2012 American Chemical Society

124.
C. K. Hazra and M. Oestreich,
Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates,
Org. Lett. 2012, 14, 4010-4013 [591]. (Abstract [592])
Highlighted in SYNFACTS 2012, 8, 1239 [593].

[594]

© John Wiley & Sons, Ltd

123.
M. Mewald and M. Oestreich,
1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene,
in Electronic Encyclopedia of Reagents for Organic Synthesis [595] (Eds.: D. Crich, P. L. Fuchs, A. B. Charette, and T. Rovis), Wiley, Chichester, 2012. (Abstract [596])

[597]

© John Wiley & Sons, Ltd

122.
M. Mewald and M. Oestreich,
1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene,
in Electronic Encyclopedia of Reagents for Organic Synthesis [598] (Eds.: D. Crich, P. L. Fuchs, A. B. Charette, and T. Rovis), Wiley, Chichester, 2012. (Abstract [599])

[600]

© 2012 Wiley-VCH

121.
A. Weickgenannt and M. Oestreich,
The Renaissance of Silicon-Stereogenic Silanes: A Personal Account,
in Asymmetric Synthesis - More Methods and Applications [601] (Eds.: M. Christmann and S. Bräse), Wiley-VCH, Weinheim, 2012, 35-42.

[602]

© 2012 American Chemical Society

120.
C. D. F. Königs, H. F. T. Klare, Y. Ohki, K. Tatsumi, and M. Oestreich,
Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes,
Org. Lett. 2012, 14, 2842-2845 [603]. (Abstract [604])
Included into Organic Chemistry Highlights under www.organic-chemistry.org [605].

[606]

© 2012 American Chemical Society

119.
E. Hartmann and M. Oestreich,
Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles,
Org. Lett. 2012, 14, 2406-2409 [607]. (Abstract [608])

[609]

© 2012 WILEY-VCH

118.
M. Oestreich,
Organic Reactions, Volume 75 (Diamond Volume). Edited by Scott E. Denmark. Wiley, Hoboken 2012 (Book Review),
Angew. Chem. 2012, 124, 4344;
Angew. Chem. Int. Ed. 2012, 51, 4270 [610]. (Abstract [611])

[612]

© 2011 Elsevier Ltd.

117.
A. Weickgenannt, J. Mohr, and M. Oestreich,
Catalytic enantioselective dehydrogenative Si-O coupling of oxime ether-functionalized alcohols
(Tetrahedron Symposium-in-Print "New Trends in Enantioselective Catalysis with Copper(I)"),
Tetrahedron 2012, 68, 3468-3479 [613]. (Abstract [614])

[615]

© 2012 American Chemical Society

116.
R. K. Schmidt, K. Müther, C. Mück-Lichtenfeld, S. Grimme, and M. Oestreich,
Silylium Ion-Catalyzed Challenging Diels-Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids,
J. Am. Chem. Soc. 2012, 134, 4421-4428 [616]. (Abstract [617])

[618]

© 2012 WILEY-VCH

115.
M. Mewald, J. A. Schiffner, and M. Oestreich,
A New Direction in C-H Alkenylation: Silanol as a Helping Hand (Highlight),
Angew. Chem. 2012, 124, 1797-1799;
Angew. Chem. Int. Ed. 2012, 51, 1763-1765 [619]. (Abstract [620])

[621]

© 2012 WILEY-VCH

114.
S. R. Kandukuri, J. A. Schiffner, and M. Oestreich,
Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds,
Angew. Chem. 2012, 124, 1291-1295;
Angew. Chem. Int. Ed. 2012, 51, 1265-1269 [622]. (Abstract [623])

2011

[624]

© 2011 WILEY-VCH

113.
C. Kleeberg, E. Feldmann, E. Hartmann, D. J. Vyas, and M. Oestreich,
Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems,
Chem. Eur. J. 2011, 17, 13538-13543 [625]. (Abstract [626])

[627]

© 2011 WILEY-VCH

112.
T. H. Wöste and M. Oestreich,
BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial Effects on Selectivities,
Chem. Eur. J. 2011, 17, 11914-11918 [628]. (Abstract [629])

[630]

© 2011 WILEY-VCH

111.
A. Weickgenannt and M. Oestreich,
A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters (Highlight),
ChemCatChem 2011, 3, 1527-1529 [631]. (Abstract [632])

[633]

© 2011 American Chemical Society

110.
D. J. Vyas, C. K. Hazra, and M. Oestreich,
Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si-B Bond Activation,
Org. Lett. 2011, 13, 4462-4465 [634]. (Abstract [635])
Included into Organic Chemistry Highlights under www.organic-chemistry.org [636].

[637]

© 2011 Teknoscienze S.r.l.

109.
E. Hartmann and M. Oestreich,
Si-B Bond Activation in Asymmetric Cu(I) and Rh(I) Catalysis,
Chemistry TODAY / Chimica OGGI 2011, 29, 34-36 (September/October issue).

[638]

© 2011 American Chemical Society

108.
K. Müther, R. Fröhlich, C. Mück-Lichtenfeld, S. Grimme, and M. Oestreich,
A Unique Transition Metal-Stabilized Silicon Cation,
J. Am. Chem. Soc. 2011, 133, 12442-12444 [639]. (Abstract [640])
Highlighted in Nachr. Chem. 2012, 60, 216-250 [641].
Highlighted in Angew. Chem. Int. Ed. 2012, 51, 4526-4528 [642].

[643]

© 2011 WILEY-VCH

107.
M. Mewald, R. Fröhlich, and M. Oestreich,
An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity,
Chem. Eur. J. 2011, 17, 9406-9414 [644]. (Abstract [645])

[646]

© The Royal Society of Chemistry 2011

106.
E. Hartmann, D. J. Vyas, and M. Oestreich,
Enantioselective formal hydration of α,β-unsaturated acceptors: Asymmetric conjugate addition of silicon and boron nucleophiles (Feature Article),
Chem. Commun. 2011, 47, 7917-7932 [647]. (Abstract [648])

[649]

© Georg Thieme Verlag

105.
C. D. F. Königs and M. Oestreich,
Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane (Practical Synthetic Procedure),
Synthesis 2011, 2062-2065 [650]. (Abstract [651])

[652]

© 2011 American Chemical Society

104.
D. J. Vyas, R. Fröhlich, and M. Oestreich,
Activation of the Si-B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines,
Org. Lett. 2011, 13, 2094-2097 [653]. (Abstract [654])

[655]

© 2011 American Chemical Society

103.
H. F. T. Klare, M. Oestreich, J.-i. Ito, H. Nishiyama, Y. Ohki, and K. Tatsumi,
Cooperative Catalytic Activation of Si–H Bonds by a Polar Ru–S Bond: Regioselective Low-Temperature C–H Silylation of Indoles under Neutral Conditions by a Friedel–Crafts Mechanism,
J. Am. Chem. Soc. 2011, 133, 3312-3315 [656]. (Abstract [657])

[658]

© 2011 Gesellschaft Deutscher Chemiker

102.
M. Oestreich,
Trendbericht 2010 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2011, 59, 264 [659]. (Abstract [660])

[661]

© 2011 WILEY-VCH

101.
J. A. Schiffner and M. Oestreich,
All Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)-Catalyzed Ring Closure onto Tri- and Tetrasubstituted Double Bonds,
Eur. J. Org. Chem. 2011, 1148-1154 [662]. (Abstract [663])
Selected as EurBest in EurJOC.

[664]

© The Royal Society of Chemistry 2011

100.
K. Müther and M. Oestreich,
Self-regeneration of a silylium ion catalyst in carbonyl reduction,
Chem. Commun. 2011, 47, 334-336 [665]. (Abstract [666])
Part of the "Emerging Investigators" Themed Issue of Chemical Communications.
Highlighted in Angew. Chem. Int. Ed. 2012, 51, 4526-4528 [667].

2010

[668]

© 2010 WILEY-VCH

99.
D. J. Vyas and M. Oestreich,
Copper-Catalyzed Si-B Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides,
Angew. Chem. 2010, 122, 8692-8694;
Angew. Chem. Int. Ed. 2010, 49, 8513-8515 [669]. (Abstract [670])
Editors' Choice: ChemInform. [671]

[672]

© 2010 American Chemical Society

98.
D. J. Vyas, R. Fröhlich, and M. Oestreich,
Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins,
J. Org. Chem. 2010, 75, 6720-6723 [673]. (Abstract [674])

[675]

© Georg Thieme Verlag

97.
A. Grajewska and M. Oestreich,
Base-Catalyzed Dehydrogenative Si-O Coupling with Dihydrosilanes: Silylene Protection of Diols,
Synlett 2010, 2482-2484 [676]. (Abstract [677])

[678]

© 2010 The Royal Society of Chemistry

96.
H. F. T. Klare and M. Oestreich,
Silylium ions in catalysis (Perspective),
(Special Issue "New Horizon of Organosilicon Chemistry"),
Dalton Trans. 2010, 39, 9176-9184 [679]. (Abstract [680])

[681]

© 2010 WILEY-VCH

95.
E. Hartmann and M. Oestreich,
Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide,
Angew. Chem. 2010, 122, 6331-6334;
Angew. Chem. Int. Ed. 2010, 49, 6195-6198 [682]. (Abstract [683])

[684]

© Georg Thieme Verlag

94.
F. M. J. Tappe, V. T. Trepohl, and M. Oestreich,
Transition Metal-Catalyzed C-P Cross-Coupling Reactions (Review),
Synthesis 2010, 3037-3062 [685]. (Abstract [686])

[687]

© 2010 Elsevier Ltd.

93.
M. Mewald, A. Weickgenannt, R. Fröhlich, and M. Oestreich,
Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
(Special Issue dedicated to Professor Henri B. Kagan on the occasion of his 80th birthday),
Tetrahedron: Asymmetry 2010, 21, 1232-1237 [688]. (Abstract [689])

[690]

© The Royal Society of Chemistry 2010

92.
A. Weickgenannt, M. Mewald, and M. Oestreich,
Asymmetric Si-O coupling of alcohols (Emerging Area),
Org. Biomol. Chem. 2010, 8, 1497-1504 [691]. (Abstract [692])
Featured on the Inside Cover of Organic & Biomolecular Chemistry.

[693]

© 2010 WILEY-VCH

91.
A. Weickgenannt, M. Mewald, T. W. T. Muesmann, and M. Oestreich,
Catalytic Asymmetric Si-O Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols,
Angew. Chem. 2010, 122, 2269-2272;
Angew. Chem. Int. Ed. 2010, 49, 2223-2226 [694]. (Abstract [695])
Highlighted in SYNFACTS 2010, 549 [696].

[697]

© 2010 Gesellschaft Deutscher Chemiker

90.
M. Oestreich,
Trendbericht 2009 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2010, 58, 278 [698]. (Abstract [699])

[700]

© 2010 WILEY-VCH

89.
J. A. Schiffner, K. Müther, and M. Oestreich,
Enantioselective Conjugate Borylation (Highlight),
Angew. Chem. 2010, 122, 1214-1216;
Angew. Chem. Int. Ed. 2010, 49, 1194-1196 [701]. (Abstract [702])

[703]

© The Royal Society of Chemistry 2010

88.
D. J. Vyas and M. Oestreich,
Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides,
Chem. Commun. 2010, 46, 568-570 [704]. (Abstract [705])
Selected a "Hot Article" by Chemical Communications.

[706]

© 2010 WILEY-VCH

87.
A. Weickgenannt and M. Oestreich,
Silicon- and Tin-Based Cuprates: Now Catalytic in Copper! (Concept),
Chem. Eur. J. 2010, 16, 402-412 [707]. (Abstract [708])
Editors' Choice: Spotlights.

[709]

© 2010 WILEY-VCH

86.
J. A. Schiffner, T. H. Wöste, and M. Oestreich,
Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes,
Eur. J. Org. Chem. 2010, 174-182 [710]. (Abstract [711])

2009

[712]

© 2009 WILEY-VCH

85.
H. F. T. Klare, K. Bergander, and M. Oestreich,
Taming the Silylium Ion for Low-Temperature Diels–Alder Reactions,
Angew. Chem. 2009, 121, 9241-9243;
Angew. Chem. Int. Ed. 2009, 48, 9077-9079 [713]. (Abstract [714])
Highlighted in Nachr. Chem. 2010, 58, 7 [715].
Highlighted in Angew. Chem. Int. Ed. 2012, 51, 4526-4528 [716].

[717]

© 2009 WILEY-VCH

84.
D. T. Hog and M. Oestreich,
B(C₆F₅)₃-Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding,
Eur. J. Org. Chem. 2009, 5047-5056 [718]. (Abstract [719])
Editors' Choice: Spotlights.

[720]

© The Royal Society of Chemistry 2009

83.
A. Steves and M. Oestreich,
Facile preparation of CF₃-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si-O coupling,
Org. Biomol. Chem. 2009, 7, 4464-4469 [721]. (Abstract [722])

[723]

© 2009 Elsevier Ltd.

82.
V. T. Trepohl, R. Fröhlich, and M. Oestreich,
Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)-phosphine and Rh(I)-carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si-P reagent
(Tetrahedron Symposium-in-Print "2008 Tetrahedron Prize for Creativity in Organic Chemistry to Larry E. Overman"),
Tetrahedron 2009, 65, 6510-6518 [724]. (Abstract [725])

[726]

© 2009 Elsevier Ltd.

81.
C. Walter, R. Fröhlich, and M. Oestreich,
Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
(Tetrahedron Symposium-in-Print "Recent Advances in Organosilicon Chemistry Directed towards Organic Synthesis"),
Tetrahedron 2009, 65, 5513-5520 [727]. (Abstract [728])

[729]

© 2009 WILEY-VCH

80.
E. S. Schmidtmann and M. Oestreich,
Enantiospecific Preparation and Allylation Chemistry of All-Carbon-Substituted α-Chiral Allylic Stannanes,
Angew. Chem. 2009, 121, 4705-4709;
Angew. Chem. Int. Ed. 2009, 48, 4634-4638 [730]. (Abstract [731])
Highlighted in SYNFACTS 2009, 1002 [732].

[733]

© 2009 WILEY-VCH

79.
H. F. T. Klare and M. Oestreich,
Asymmetric Ring-Closing Metathesis with a Twist (Highlight),
Angew. Chem. 2009, 121, 2119-2123;
Angew. Chem. Int. Ed. 2009, 48, 2085-2089 [734]. (Abstract [735])

[736]

© 2009 Gesellschaft Deutscher Chemiker

78.
M. Oestreich,
Trendbericht 2008 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2009, 57, 259 [737]. (Abstract [738])

[739]

© 2009 American Chemical Society

77.
V. T. Trepohl, S. Mori, K. Itami, and M. Oestreich,
Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors,
Org. Lett. 2009, 11, 1091-1094 [740]. (Abstract [741])
Included into Organic Chemistry Highlights under www.organic-chemistry.org [742].

[743]

© 2009 John Wiley & Sons

76.
M. Oestreich (Editor),
The Mizoroki-Heck Reaction [744], Wiley, Chichester, 2009 (608 pages, Hardcover).
ISBN: 978-0-470-03394-4.
Book Review: Angew. Chem. 2009, 121, 7081 [745]; Angew. Chem. Int. Ed. 2009, 48, 6947. [746]
Buchbesprechung: Nachr. Chem. 2009, 57, 1030-1031.
Book Review: Synthesis 2010, 718 [747].
Book Review: Org. Process Res. Dev. 2010, 14, 748 [748].
Book Review: Appl. Organometal. Chem. 2010, 24, 490 [749].

[750]

© 2009 John Wiley & Sons

75.
A. B. Machotta and M. Oestreich,
Intramolecular Heck Reaction - Formation of Carbocycles,
in The Mizoroki-Heck Reaction [751] (Ed.: M. Oestreich), Wiley, Chichester, 2009, 179-213.

[752]

© 2009 WILEY-VCH

74.
A. Weickgenannt and M. Oestreich,
Potassium tert-Butoxide-Catalyzed Dehydrogenative Si-O Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection,
Chem. Asian J. 2009, 4, 406-410 [753]. (Abstract [754])

[755]

© 2009 John Wiley & Sons

73.
V. T. Trepohl and M. Oestreich,
Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki-Heck Reaction and Related Processes),
in Modern Arylation Methods [756] (Ed.: L. Ackermann), Wiley-VCH, Weinheim, 2009, 221-269.

2008

[757]

© 2008 WILEY-VCH

72.
S. Rendler, O. Plefka, B. Karatas, G. Auer, R. Fröhlich, C. Mück-Lichtenfeld, S. Grimme, and M. Oestreich,
Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes,
Chem. Eur. J. 2008, 14, 11512-11528 [758]. (Abstract [759])

[760]

© Springer

71.
R. Brückner, H.-D. Beckhaus, S. Braukmüller, J. Dirksen, D. Goeppel und M. Oestreich,
Praktikum Präparative Organische Chemie - Organisch-Chemisches Fortgeschrittenenpraktikum [761],
Spektrum Akademischer Verlag, Heidelberg, 2009 (374 Seiten, 424 Abbildungen, Softcover) (published in 2008).
ISBN: 978-3-8274-1981-1.

[762]

© Georg Thieme Verlag

70.
J. A. Schiffner, A. B. Machotta, and M. Oestreich,
A Catalytic Asymmetric Fujiwara-Moritani Cyclization,
Synlett 2008, 2271-2274 [763]. (Abstract [764])

[765]

© WILEY-VCH

69.
S. Rendler and M. Oestreich,
Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Carbonyl Hydrosilylation: Implications for the Related Hydrogenation,
Angew. Chem. 2008, 120, 6086-6089;
Angew. Chem. Int. Ed. 2008, 47, 5997-6000 [766]. (Abstract [767])

[768]

© Georg Thieme Verlag

68.
R. K. Schmidt and M. Oestreich,
Transition Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carboxyl Compounds in Basic Aqueous Media,
Synlett 2008, 1690-1692 [769]. (Abstract [770])

[771]

© 2008 WILEY-VCH

67.
S. Rendler, R. Fröhlich, M. Keller, and M. Oestreich,
Enantio- and Diastereotopos-Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes,
Eur. J. Org. Chem. 2008, 2582-2591 [772]. (Abstract [773])
Highlighted in SYNFACTS 2008, 855 [774].

[775]

© 2008 WILEY-VCH

66.
C. Walter and M. Oestreich,
Catalytic Asymmetric C-Si Bond Formation by Rh(I)-Catalyzed Conjugate Silyl Transfer onto Acyclic α,β-Unsaturated Acceptors Using the Si-B Interelement Linkage,
Angew. Chem. 2008, 120, 3878-3880;
Angew. Chem. Int. Ed. 2008, 47, 3818-3820 [776]. (Abstract [777])
Highlighted in SYNFACTS 2008, 739 [778].

[779]

© 2008 WILEY-VCH

65.
A. B. Machotta and M. Oestreich,
Asymmetric Synthesis - The Essentials (Second, Completely Revised Edition). Edited by Mathias Christmann and Stefan Bräse. Wiley-VCH, Weinheim 2008 (Book Review),
Synthesis 2008, 1163 [780]. (Abstract [781])

[782]

© The Royal Society of Chemistry 2008

64.
B. Karatas, S. Rendler, R. Fröhlich, and M. Oestreich,
Kinetic Resolution of Donor-Functionalised Tertiary Alcohols by Cu-H-Catalysed Stereoselective Silylation Using a Strained Silicon-Stereogenic Silane,
Org. Biomol. Chem. 2008, 6, 1435-1440 [783]. (Abstract [784])

[785]

© Springer

63.
R. Brückner, H.-D. Beckhaus, S. Braukmüller, J. Dirksen, D. Goeppel und M. Oestreich,
Praktikum Präparative Organische Chemie - Organisch-Chemisches Grundpraktikum [786],
Spektrum Akademischer Verlag, Heidelberg, 2008 (394 Seiten, 599 Abbildungen, Softcover).
ISBN: 978-3-8274-1505-9.
Buchbesprechung: Angew. Chem. 2008, 120, 8106-8108 [787].
Buchbesprechung: Nachr. Chem. 2008, 56, 931-932 [788].

[789]

© 2008 Gesellschaft Deutscher Chemiker

62.
M. Oestreich,
Trendbericht 2007 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2008, 56, 276 [790]. (Abstract [791])

[792]

© 2008 WILEY-VCH

61.
S. Rendler and M. Oestreich,
Diverse Modes of Silane Activation for Hydrosilylation of Carbonyl Compounds,
in Modern Reduction Methods [793] (Eds.: P. G. Andersson and I. J. Munslow), Wiley-VCH, Weinheim, 2008, 183-207.

[794]

© 2008 WILEY-VCH

60.
S. Rendler and M. Oestreich,
Kinetic Resolution and Desymmetrization by Stereoselective Alcohol Silylation (Highlight),
Angew. Chem. 2008, 120, 254-257;
Angew. Chem. Int. Ed. 2008, 47, 248-250 [795]. (Abstract [796])

2007

[797]

© 2007 WILEY-VCH

59.
H. F. T. Klare and M. Oestreich,
Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols,
Angew. Chem. 2007, 119, 9496-9499;
Angew. Chem. Int. Ed. 2007, 46, 9335-9338 [798]. (Abstract [799])

[800]

© 2007 Gesellschaft Deutscher Chemiker

58.
S. Rendler and M. Oestreich,
Asymmetrische Synthese Hand in Hand: Ein Erfolgsbericht: Asymmetric Synthesis with Chemical and Biological Methods. Hrsg. von Dieter Enders und Karl-Erich Jaeger. Wiley-VCH, Weinheim 2007 (Book Review),
Nachr. Chem. 2007, 55, 1032-1033 [801]. (Abstract [802])

[803]

© 2007 American Chemical Society

57.
A. B. Machotta, B. F. Straub, and M. Oestreich,
Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene-Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations,
J. Am. Chem. Soc. 2007, 129, 13455-13463 [804]. (Abstract [805])

[806]

© The Royal Society of Chemistry 2007

56.
V. T. Trepohl and M. Oestreich,
Rhodium(I)-catalyzed Conjugate Phosphination of Cyclic α,β-Unsaturated Ketones with Silylphoshines as Masked Phosphinides,
Chem. Commun. 2007, 3300-3302 [807]. (Abstract [808])

[809]

© Georg Thieme Verlag

55.
M. Oestreich,
Silicon-Stereogenic Silanes in Asymmetric Catalysis (Account),
Synlett 2007, 1629-1643 [810]. (Abstract [811])

[812]

© Springer

54.
M. Oestreich,
Directed Mizoroki-Heck Reactions [813],
in Directed Metallation (Ed.: N. Chatani), Springer, Heidelberg,
Top. Organomet. Chem. 2007, 24, 169-192.

[814]

© 2006 WILEY-VCH

53.
A. Zimmermann and M. Oestreich,
Asymmetric Synthesis - The Essentials. Edited by Mathias Christmann and Stefan Bräse. Wiley-VCH, Weinheim, 2006 (Book Review),
Synthesis 2007, 957 [815]. (Abstract [816])

[817]

© 2007 Gesellschaft Deutscher Chemiker

52.
M. Oestreich,
Trendbericht 2006 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2007, 55, 272-273 [818]. (Abstract [819])

[820]

© Beilstein-Institut

51.
S. Rendler and M. Oestreich,
Conformational Rigidity of Silicon-Stereogenic Silanes in Asymmetric Catalysis: A Comparative Study,
(Thematic Series on Contemporary Organosilicon Chemistry),
Beilstein J. Org. Chem. 2007, 3, 9. [821] (open access) (Abstract [822])

[823]

© 2007 American Chemical Society

50.
S. Rendler, M. Oestreich, C. P. Butts, and G. C. Lloyd-Jones,
Intermolecular Chirality Transfer from Silicon to Carbon: Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Cross-over,
J. Am. Chem. Soc. 2007, 129, 502-503 [824]. (Abstract [825])
Highlighted in SYNFACTS 2007, 409. [826]

[827]

© 2007 Wiley-VCH

49.
S. Rendler and M. Oestreich,
Polishing a Diamond in the Rough: "Cu-H" Catalysis with Silanes (Minireview),
Angew. Chem. 2007, 119, 504-510;
Angew. Chem. Int. Ed. 2007, 46, 498-504 [828]. (Abstract [829])

2006

[830]

© Georg Thieme Verlag

48.
M. Oestreich,
Synthesis of Arenecarbaldehydes by C-C Bond Formation of Ar-CH=O (Product Class 6, Section 25.6.8),
in Science of Synthesis, Volume 25 (Ed.: R. Brückner), Thieme, Stuttgart, 2006, pp 667-688.

[831]

© Georg Thieme Verlag

47.
M. Oestreich,
Synthesis of Aldehydes by Hydration of Alkynes (Product Class 1, Section 25.1.8),
in Science of Synthesis, Volume 25 (Ed.: R. Brückner), Thieme, Stuttgart, 2006, pp 199-211.

[832]

© 2006 Wiley-VCH

46.
A. B. Machotta and M. Oestreich,
Organic Chemistry Online...and for Free? (Website Review),
Angew. Chem. 2006, 118, 7272;
Angew. Chem. Int. Ed. 2006, 45, 7114 [833]. (Abstract [834])

[835]

© The Royal Society of Chemistry 2006

45.
E. S. Schmidtmann and M. Oestreich,
Mechanistic Insight into Copper-Catalysed Allylic Substitutions with Bis(triorganosilyl) Zincs: Enantiospecific Preparation of α-Chiral Allylic Silanes,
Chem. Commun. 2006, 3643-3645 [836]. (Abstract [837])

[838]

© 2006 WILEY-VCH

44.
C. Walter, G. Auer, and M. Oestreich,
Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boronic Esters to Cyclic Enones and Lactones,
Angew. Chem. 2006, 118, 5803-5805;
Angew. Chem. Int. Ed. 2006, 45, 5675-5677 [839]. (Abstract [840])
Selected a "Hot Paper" by Angewandte Chemie.
Highlighted in SYNFACTS 2006, 1142 [841].
Included into Organic Chemistry Highlights under www.organic-chemistry.org [842].

[843]

© 2006 WILEY-VCH Verlag

43.
S. Rendler, G. Auer, M. Keller, and M. Oestreich,
Preparation of a Privileged Silicon-Stereogenic Silane: Classical versus Kinetic Resolution,
Adv. Synth. Catal. 2006, 348, 1171-1182 [844]. (Abstract [845])

[846]

© Georg Thieme Verlag

42.
M. Oestreich, F. Sempere-Culler, and A. B. Machotta,
An Enantioselective Access to the Anthracycline AB Synthon by a Desymmetrizing Heck Cyclization
(Special Issue dedicated to Professor Richard F. Heck),
Synlett 2006, 2965-2968 [847]. (Abstract [848])

[849]

© Georg Thieme Verlag

41.
G. Auer, B. Weiner, and M. Oestreich,
Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zincs and Tris(triorganosilyl) Zincates
(Special Issue dedicated to Professor Dieter Hoppe on the occasion of his 65th birthday),
Synthesis 2006, 2113-2116 [850]. (Abstract [851])

[852]

© 2006 Gesellschaft Deutscher Chemiker

40.
M. Oestreich,
Trendbericht 2005 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2006, 54, 254-255 [853]. (Abstract [854])

[855]

© 2006 Wiley-VCH

39.
M. Oestreich,
Quaternary Stereocenters. Edited by Jens Christoffers and Angelika Baro. Wiley-VCH, Weinheim 2005 (Book Review),
Angew. Chem. 2006, 118, 554-555;
Angew. Chem. Int. Ed. 2006, 45, 540-541 [856]. (Abstract [857])

[858]

© The Royal Society of Chemistry 2006

38.
G. Auer and M. Oestreich,
Silylzincation of Carbon-Carbon Multiple Bonds Revisited,
Chem. Commun. 2006, 311-313 [859]. (Abstract [860])

[861]

© 2006 WILEY-VCH

37.
M. Oestreich,
Chirality Transfer from Silicon to Carbon (Concept),
Chem. Eur. J. 2006, 12, 30-37 [862]. (Abstract [863])

2005

[864]

© 2005 WILEY-VCH

36.
S. Rendler, G. Auer, and M. Oestreich,
Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes,
Angew. Chem. 2005, 117, 7793-7797;
Angew. Chem. Int. Ed. 2005, 44, 7620-7624. [865] (Abstract [866])

[867]

© 2005 Gesellschaft Deutscher Chemiker

35.
A. B. Machotta and M. Oestreich,
OMCOS 13 (Conference Report),
Nachr. Chem. 2005, 53, 1069 [868]. (Abstract [869])

[870]

© 2005 WILEY-VCH Verlag

34.
M. Oestreich,
Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005 (Conference Report),
Angew. Chem. 2005, 117, 5296-5297;
Angew. Chem. Int. Ed. 2005, 44, 5166-5167 [871]. (Abstract [872])

[873]

© Georg Thieme Verlag

33.
S. Rendler and M. Oestreich,
Hypervalent Silicon as a Reactive Site in Selective Bond Forming Processes (Review),
Synthesis 2005, 1727-1747 [874]. (Abstract [875])

[876]

© 2005 WILEY-VCH Verlag

32.
M. Oestreich,
Swiss Delight: Bürgenstock 2005 (Conference Report),
Angew. Chem. 2005, 117, 3578-3580;
Angew. Chem. Int. Ed. 2005, 44, 3512-3513 [877]. (Abstract [878])

[879]

© 2005 Gesellschaft Deutscher Chemiker

31.
M. Oestreich,
Chemie-Nachwuchsgruppenleiter in Freiburg (Conference Report),
Nachr. Chem. 2005, 53, 559 [880]. (Abstract [881])

[882]

© 2005 WILEY-VCH

30.
M. Oestreich,
Strategies for Catalytic Asymmetric Electrophilic α-Halogenation of Carbonyl Compounds (Highlight),
Angew. Chem. 2005, 117, 2376-2379;
Angew. Chem. Int. Ed. 2005, 44, 2324-2327 [883]. (Abstract [884])

[885]

© 2005 WILEY-VCH Verlag

29.
M. Oestreich and G. Auer,
Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions,
Adv. Synth. Catal. 2005, 347, 637-640 [886]. (Abstract [887])

[888]

© 2005 WILEY-VCH

28.
M. Oestreich and S. Rendler,
"True" Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent-controlled Palladium-catalyzed Hydrosilylation,
Angew. Chem. 2005, 117, 1688-1691;
Angew. Chem. Int. Ed. 2005, 44, 1661-1664 [889]. (Abstract [890])
Highlighted in SYNFACTS 2005, 39 (Pilot Issue) [891].

[892]

© 2005 Gesellschaft Deutscher Chemiker

27.
M. Oestreich,
Trendbericht 2004 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2005, 53, 267 [893]. (Abstract [894])

[895]

© 2005 WILEY-VCH

26.
M. Oestreich,
Neighbouring Group Effects in Heck Reactions (Review),
Eur. J. Org. Chem. 2005, 783-792 [896]. (Abstract [897])

[898]

© 2005 WILEY-VCH

25.
M. Oestreich, G. Auer, and M. Keller,
On the Mechanism of the Reductive Metalation of Asymmetrically Substituted Silyl Chlorides,
Eur. J. Org. Chem. 2005, 184-195 [899]. (Abstract [900])

[901]

© 2005 WILEY-VCH

24.
M. Oestreich, F. Sempere-Culler, and A. B. Machotta,
Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-directed Migratory Insertion,
Angew. Chem. 2005, 117, 152-155;
Angew. Chem. Int. Ed. 2005, 44, 149-152 [902]. (Abstract [903])

2004

[904]

© 2004 Gesellschaft Deutscher Chemiker

23.
M. Oestreich,
Synthese im Blickpunkt: Phosphine: Chemische Alleskönner?,
Nachr. Chem. 2004, 52, 1257-1260 [905]. (Abstract [906])

[907]

© 2004 Gesellschaft Deutscher Chemiker

22.
M. Oestreich,
Synthese im Blickpunkt: Biomimetische Diterpen-Synthesen,
Nachr. Chem. 2004, 52, 1050-1055 [908]. (Abstract [909])

[910]

© Georg Thieme Verlag

21.
M. Oestreich and B. Weiner,
Copper-catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorganosilyl) Magnesium,
Synlett 2004, 2139-2142 [911]. (Abstract [912])

[913]

© 2004 Gesellschaft Deutscher Chemiker

20.
M. Oestreich,
Synthese im Blickpunkt: Niedervalentes Titan: der Herr der kleinen Ringe,
Nachr. Chem. 2004, 52, 805-808 [914]. (Abstract [915])

[916]

© 2004 Gesellschaft Deutscher Chemiker

19.
M. Oestreich,
Synthese im Blickpunkt: Wege zu (-)-Galanthamin,
Nachr. Chem. 2004, 52, 688-691 [917]. (Abstract [918])

[919]

© 2004 Gesellschaft Deutscher Chemiker

18.
M. Oestreich,
Synthese im Blickpunkt: Ein neues Eisen im Feuer,
Nachr. Chem. 2004, 52, 446-449 [920]. (Abstract [921])

[922]

© The Royal Society of Chemistry 2004

17.
M. Oestreich and F. Sempere-Culler,
Facile Protocol for the Highly Regioselective and Stereodivergent Synthesis of Substituted Bishomoallylic Alcohols from Esters,
Chem. Commun. 2004, 692-693 [923]. (Abstract [924])

[925]

© 2004 Gesellschaft Deutscher Chemiker

16.
M. Oestreich,
Trendbericht 2003 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2004, 52, 282-283 [926]. (Abstract [927])

[928]

© 2004 Gesellschaft Deutscher Chemiker

15.
M. Oestreich,
Der Triumphzug der Metathese in drei Bänden: Handbook of Metathesis. Vol. 1-3. Hrsg. von Robert H. Grubbs. Wiley-VCH, Weinheim 2003 (Book Review),
Nachr. Chem. 2004, 52, 184-185 [929]. (Abstract [930])

[931]

© 2004 Gesellschaft Deutscher Chemiker

14.
M. Oestreich,
23. Regio-Symposium in Falkau/Schwarzwald (Conference Report),
Nachr. Chem. 2004, 52, 64 [932]. (Abstract [933])

[934]

© 2004 Gesellschaft Deutscher Chemiker

13.
M. Oestreich,
Synthese im Blickpunkt: Das andere Gesicht der Organokatalyse,
Nachr. Chem. 2004, 52, 35-38 [935]. (Abstract [936])

2003

[937]

© Georg Thieme Verlag

12.
M. Oestreich, U. K. Schmid, G. Auer, and M. Keller,
A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silanes with Silicon-Centered Chirality (Feature Article),
Synthesis 2003, 2725-2739 [938]. (Abstract [939])

[940]

© 2003 Gesellschaft Deutscher Chemiker

11.
M. Oestreich,
Trendbericht 2002 - Organische Chemie: Metallfreie Synthesemethoden,
Nachr. Chem. 2003, 51, 298-300 [941]. (Abstract [942])

1999

[943]

© 2014 WILEY-VCH

10.
M. Oestreich and E. Droste,
Hochreaktive Mehrfachbindungssysteme: Theorie und Experiment (Conference Report),
Nachr. Chem. Tech. Lab. 1999, 47, 219 [944]. (Abstract [945])

Publications with Professor Larry E. Overman

9.
A. B. Dounay, K. Hatanaka, J. J. Kodanko, M. Oestreich, L. E. Overman, L. A. Pfeifer, and M. M. Weiss,
Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions,
J. Am. Chem. Soc. 2003, 125, 6261-6271 [946]. (Abstract [947])

8.
M. Oestreich, P. R. Dennison, J. J. Kodanko, and L. E. Overman,
Thwarting β-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction,
Angew. Chem. 2001, 113, 1485-1489;
Angew. Chem. Int. Ed. 2001, 40, 1439-1442 [948]. (Abstract [949])

Publications with Professor Dieter Hoppe

7.
M. Oestreich and D. Hoppe,
Stereospecific Preparation of Highly Enantiomerically Enriched Organomagnesium Reagents (Review and Commentary),
Chemtracts - Organic Chemistry 2001, 14, 100-105.

6.
M. Oestreich, R. Fröhlich, and D. Hoppe,
(-)-Sparteine-mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene Cyclopentanes,
J. Org. Chem. 1999, 64, 8616-8626 [950]. (Abstract [951])

5.
D. Hoppe, M. J. Woltering, M. Oestreich, and R. Fröhlich,
(-)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of Alkenes: Synthesis of Enantiopure Cyclopentanes with Three Consecutive Stereogenic Centers,
Helv. Chim. Acta 1999, 82, 1860-1877 [952]. (Abstract [953])

4.
M. Oestreich and D. Hoppe,
(-)-Sparteine-mediated Stereoselective Intramolecular Conjugate Addition Reactions of Dienes and Enynes,
Tetrahedron Lett. 1999, 40, 1881-1884 [954]. (Abstract)
[955]Corrigendum, Tetrahedron Lett. 1999, 40, 3283 [956]. (Abstract [957])

3.
M. Oestreich, R. Fröhlich, and D. Hoppe,
(-)-Sparteine-mediated Stereoselective Intramolecular Carbolithiation of Alkynes,
Tetrahedron Lett. 1998, 39, 1745-1748 [958]. (Abstract [959])

Publications with Professor Paul Knochel

2.
A. Boudier, C. Darcel, F. Flachsmann, L. Micouin, M. Oestreich, and P. Knochel,
Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds,
Chem. Eur. J. 2000, 6, 2748-2761 [960]. (Abstract [961])

1.
L. Micouin, M. Oestreich, and P. Knochel,
Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds,
Angew. Chem. 1997, 109, 275-276;
Angew. Chem. Int. Ed. 1997, 36, 245-246 [962]. (Abstract [963])