© AK Oestreich

Publications

© 2022 WILEY-VCH

49.
T. He, Z.-W. Qu,* H. F. T. Klare, S. Grimme, and M. Oestreich*,
Intermolecular Carbosilylation of α-Olefins with C(sp³)–C(sp) Bond Formation Involving Silylium-Ion Regeneration,
Angew. Chem. 2022, 132, e202203347;
Angew. Chem. Int. Ed. 2022, 61, e202203347. (Abstract)
Selected as a "Hot Paper" by Angewandte Chemie.
(open access)

© 2022 American Chemical Society

48.
S. Elangovan, E. Irran, H. F. T. Klare,* and M. Oestreich*,
Cationic Cobalt–Thiolate Complexes for the Dehydrogenative Coupling of nBu₃SnH,
Organometallics 2022, 41, 852-857. (Abstract)

© 2022 American Chemical Society

47.
T. He, H. F. T. Klare,* and M. Oestreich*,
Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis,
J. Am. Chem. Soc. 2022, 144, 4734-4738. (Abstract)

© 2022 American Chemical Society

46.
S. Rej, H. F. T. Klare, and M. Oestreich*,
Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate,
Org. Lett. 2022, 24, 1346-1350. (Abstract)

© 2022 WILEY-VCH

45.
H. Gao, R. Müller, E. Irran, H. F. T. Klare, M. Kaupp,* and M. Oestreich*,
Competition for Hydride between Silicon and Boron: Synthesis and Characterization of a Hydroborane-Stabilized Silylium Ion,
Chem. Eur. J. 2022, 28, e202104464. (Abstract)
(open access)

© 2021 American Chemical Society

44.
T. He, H. F. T. Klare,* and M. Oestreich*,
Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization,
ACS Catal. 2021, 11, 12186-12193. (Abstract)

© 2021 American Chemical Society

43.
H. F. T. Klare* and M. Oestreich*,
The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis (Perspective),
J. Am. Chem. Soc. 2021, 143, 15490-15507. (Abstract)

© 2021 ACS / Martin Oestreich

42.
H. F. T. Klare,* L. Albers, L. Süsse, S. Keess, T. Müller,* and M. Oestreich*,
Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts (Review),
Chem. Rev. 2021, 121, 5889-5985. (Abstract)

© 2020 Royal Society of Chemistry

41.
T. He, G. Wang, P.-W. Long, S. Kemper, E. Irran, H. F. T. Klare,* and M. Oestreich*,
Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes,
Chem. Sci. 2021, 12, 569-575. (Abstract)
Selected for the 2020 Chemical Science HOT Article Collection.
(open access)
Highlighted in SYNFACTS 2021, 17, 623.

© 2020 American Chemical Society

40.
M. Oberling, E. Irran, Y. Ohki,* H. F. T. Klare,* and M. Oestreich*,
Cationic Ru–Se Complexes for Cooperative Si–H Bond Activation,
Organometallics 2020, 39, 4747-4753. (Abstract)

© 2020 WILEY-VCH

39.
T. He, G. Wang, V. Bonetti, H. F. T. Klare, and M. Oestreich*,
Silylium-Ion-Promoted (5+1) Cycloaddition of Aryl-Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration,
Angew. Chem. 2020, 132, 12284-12289;
Angew. Chem. Int. Ed. 2020, 59, 12186-12191. (Abstract)
(open access)

© 2020 WILEY-VCH

38.
Q. Wu, A. Roy, G. Wang, E. Irran, H. F. T. Klare, and M. Oestreich*,
Synthesis of a Counteranion-Stabilized Bis(silylium) Ion,
Angew. Chem. 2020, 132, 10609-10613;
Angew. Chem. Int. Ed. 2020, 59, 10523-10526. (Abstract)
Highlighted as a "Very Important Paper (VIP)" by Angewandte Chemie.
(open access)

© 2020 MDPI

37.
H. Yehia, S. Westarp, V. Röhrs, F. Kaspar, R. T. Giessmann, H. F. T. Klare, K. Paulick, P. Neubauer, J. Kurreck, and A. Wagner*,
Efficient Biocatalytic Synthesis of Dihalogenated Purine Nucleoside Analogues Applying Thermodynamic Calculations,
Molecules 2020, 25, 934. (Abstract)
(open access)

© 2020 American Chemical Society

36.
A. Roy, V. Bonetti, G. Wang, Q. Wu, H. F. T. Klare, and M. Oestreich*,
Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes,
Org. Lett. 2020, 22, 1213-1216. (Abstract)

© 2020 Springer Nature Limited

35.
J. C. L. Walker, H. F. T. Klare, and M. Oestreich*,
Cationic silicon Lewis acids in catalysis (Perspective),
Nat. Rev. Chem. 2020, 4, 54-62. (Abstract)
Commentary: Nat. Rev. Chem. 2020, 4, 4-5.

© 2019 American Chemical Society

34.
J. Fuchs, E. Irran, P. Hrobárik,* H. F. T. Klare,* and M. Oestreich*,
Si–H Bond Activation with Bullock's Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand,
J. Am. Chem. Soc. 2019, 141, 18845-18850. (Abstract)

© 2019 WILEY-VCH

33.
Q. Wu, A. Roy, E. Irran, Z.-W. Qu,* S. Grimme, H. F. T. Klare, and M. Oestreich*,
Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions,
Angew. Chem. 2019, 131, 17468-17472;
Angew. Chem. Int. Ed. 2019, 58, 17307-17311. (Abstract)
Highlighted as a "Very Important Paper (VIP)" by Angewandte Chemie.
(open access)
Highlighted in SYNFACTS 2019, 15, 1427.

© 2019 AAAS

32.
Q. Wu, E. Irran, R. Müller, M. Kaupp, H. F. T. Klare,* and M. Oestreich*,
Characterization of hydrogen-substituted silylium ions in the condensed phase,
Science 2019, 365, 168-172. (Abstract)
Highlighted in Nachr. Chem. 2019, 67, 47.
Highlighted in Nachr. Chem. 2020, 68, 50-64.

© 2018 WILEY-VCH

31.
A. Merk, H. Großekappenberg, M. Schmidtmann, M.-P. Luecke, C. Lorent, M. Driess, M. Oestreich, H. F. T. Klare,* and T. Müller*,
Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs,
Angew. Chem. 2018, 130, 15487-15492;
Angew. Chem. Int. Ed. 2018, 57, 15267-15271. (Abstract)
Highlighted in Nat. Rev. Chem. 2018, 2, 255.
Highlighted in Nachr. Chem. 2020, 68, 50-64.

© 2018 Elsevier

30.
S. Kamel, M. Weiß, H. F. T. Klare, I. A. Mikhailopulo, P. Neubauer, and A. Wagner*,
Chemo-enzymatic synthesis of α-D-pentofuranose-1-phosphates using thermostable pyrimidine nucleoside phosphorylases,
Mol. Catal. 2018, 458, 52-59. (Abstract)

© 2018 WILEY-VCH

29.
Q. Wu, Z.-W. Qu,* L. Omann, E. Irran, H. F. T. Klare, and M. Oestreich*,
Cleavage of Unactivated Si‒C(sp³) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions,
Angew. Chem. 2018, 130, 9317-9320;
Angew. Chem. Int. Ed. 2018, 57, 9176-9179. (Abstract)
Highlighted in Nachr. Chem. 2018, 66, 942.

© 2018 Royal Society of Chemistry

28.
L. Omann, B. Pudasaini, E. Irran, H. F. T. Klare, M.-H. Baik,* and M. Oestreich*,
Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion,
Chem. Sci. 2018, 9, 5600-5607. (Abstract)
Selected for the 2018 Chemical Science HOT Article Collection.
(open access)

© 2018 WILEY-VCH

27.
L. Omann, Z.-W. Qu, E. Irran, H. F. T. Klare,* S. Grimme,* and M. Oestreich*,
Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide,
Angew. Chem. 2018, 130, 8433-8437;
Angew. Chem. Int. Ed. 2018, 57, 8301-8305. (Abstract)

© 2017 American Chemical Society

26.
J. Fuchs, H. F. T. Klare, and M. Oestreich*,
Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst,
ACS Catal. 2017, 7, 8338-8342. (Abstract)

© 2017 American Chemical Society

25.
H. F. T. Klare*,
Catalytic C–H Arylation of Unactivated C–H Bonds by Silylium Ion-Promoted C(sp²)–F Bond Activation (Perspective),
ACS Catal. 2017, 7, 6999-7002. (Abstract)

© 2017 American Chemical Society

24.
L. Omann, C. D. F. Königs, H. F. T. Klare,* and M. Oestreich*,
Cooperative Catalysis at Metal–Sulfur Bonds (Account),
Acc. Chem. Res. 2017, 50, 1258-1269. (Abstract)

© 2017 American Chemical Society

23.
W.-B. Liu, D. P. Schuman, Y.-F. Yang, A. A. Toutov, Y. Liang, H. F. T. Klare, N. Nesnas, M. Oestreich, D. G. Blackmond, S. C. Virgil, S. Banerjee, R. N. Zare, R. H. Grubbs, K. N. Houk,* and B. M. Stoltz*,
Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study,
J. Am. Chem. Soc. 2017, 139, 6867-6879. (Abstract)

© 2017 American Chemical Society

22.
H. F. T. Klare, A. F. G. Goldberg, D. C. Duquette, and B. M. Stoltz*,
Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives,
Org. Lett. 2017, 19, 988-991. (Abstract)

© 2017 WILEY-VCH

21.
Q. Yin, H. F. T. Klare,* and M. Oestreich*,
Catalytic Friedel–Crafts C–H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes,
Angew. Chem. 2017, 129, 3766-3771;
Angew. Chem. Int. Ed. 2017, 56, 3712-3717. (Abstract)
Highlighted in SYNFACTS 2017, 13, 529.

© 2016 AAAS

20.
H. F. T. Klare and M. Oestreich*,
Teaching nature the unnatural (Perspective),
Science 2016, 354, 970. (Abstract)

© 2016 WILEY-VCH

19.
Q. Yin, S. Kemper, H. F. T. Klare,* and M. Oestreich*,
Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6F5)3 Cannot Do!,
Chem. Eur. J. 2016, 22, 13840-13844. (Abstract)

© 2016 American Chemical Society

18.
Q.-A. Chen, H. F. T. Klare, and M. Oestreich*,
Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation,
J. Am. Chem. Soc. 2016, 138, 7868-7871. (Abstract)
ACS AuthorChoice (open access)

© 2016 WILEY-VCH

17.
R. K. Schmidt, H. F. T. Klare, R. Fröhlich, and M. Oestreich*,
Planar Chiral, Ferrocene-Stabilized Silicon Cations,
Chem. Eur. J. 2016, 22, 5376-5383. (Abstract)

© 2016 WILEY-VCH

16.
Q. Yin, H. F. T. Klare, and M. Oestreich*,
Friedel–Crafts-Type Intermolecular C–H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts,
Angew. Chem. 2016, 128, 3256-3260;
Angew. Chem. Int. Ed. 2016, 55, 3204-3207. (Abstract)

© 2015 Royal Society of Chemistry

15.
T. Stahl, P. Hrobárik,* C. D. F. Königs, Y. Ohki, K. Tatsumi, S. Kemper, M. Kaupp, H. F. T. Klare,* and M. Oestreich*,
Mechanism of the cooperative Si–H bond activation at Ru–S bonds,
Chem. Sci. 2015, 6, 4324-4334. (Abstract)
(open access)

© 2014 American Chemical Society

14.
V. H. G. Rohde, P. Pommerening, H. F. T. Klare, and M. Oestreich*,
Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts,
Organometallics 2014, 33, 3618-3628. (Abstract)

© 2014 American Chemical Society

13.
T. T. Metsänen, P. Hrobárik,* H. F. T. Klare, M. Kaupp, and M. Oestreich*,
Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart's Cationic Iridium(III) Pincer Complex,
J. Am. Chem. Soc. 2014, 136, 6912-6915. (Abstract)
Highlighted in ChemCatChem 2014, 6, 2486-2489.

© 2014 WILEY-VCH

12.
J. Hermeke, H. F. T. Klare, and M. Oestreich*,
Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative Si–N Coupling
(ISOS XVII Conference Issue New Frontiers and Challenges in Silicon Chemistry),
Chem. Eur. J. 2014, 20, 9250-9254. (Abstract)

© 2013 WILEY-VCH

11.
C. D. F. Königs, H. F. T. Klare, and M. Oestreich*,
Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners,
Angew. Chem. 2013, 125, 10260-10263;
Angew. Chem. Int. Ed. 2013, 52, 10076-10079. (Abstract)
Selected as a "Hot Paper" by Angewandte Chemie.

© 2013 American Chemical Society

10.
T. Stahl, H. F. T. Klare,* and M. Oestreich*,
Main-Group Lewis Acids for C–F Bond Activation (Perspective),
ACS Catal. 2013, 3, 1578-1587. (Abstract)
Featured on the Cover of ACS Catalysis.

© 2013 The Royal Society of Chemistry

9.
C. D. F. Königs, M. F. Müller, N. Aiguabella, H. F. T. Klare, and M. Oestreich*,
Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base,
Chem. Commun. 2013, 49, 1506-1508. (Abstract)

© 2013 American Chemical Society

8.
T. Stahl, H. F. T. Klare, and M. Oestreich*,
C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle,
J. Am. Chem. Soc. 2013, 135, 1248-1251. (Abstract)

© Verlag der Zeitschrift für Naturforschung

7.
W. Nie, H. F. T. Klare, M. Oestreich, R. Fröhlich, G. Kehr, and G. Erker*,
Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
(Special Issue dedicated to Professor Heribert Offermanns),
Z. Naturforsch. 2012, 67b, 987-994. (Abstract)

© 2012 American Chemical Society

6.
C. D. F. Königs, H. F. T. Klare, Y. Ohki,* K. Tatsumi,* and M. Oestreich*,
Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes,
Org. Lett. 2012, 14, 2842-2845. (Abstract)
Included into Organic Chemistry Highlights under www.organic-chemistry.org.

© 2011 American Chemical Society

5.
H. F. T. Klare, M. Oestreich,* J.-i. Ito, H. Nishiyama, Y. Ohki,* and K. Tatsumi*,
Cooperative Catalytic Activation of Si–H Bonds by a Polar Ru–S Bond: Regioselective Low-Temperature C–H Silylation of Indoles under Neutral Conditions by a Friedel–Crafts Mechanism,
J. Am. Chem. Soc. 2011, 133, 3312-3315. (Abstract)

© 2010 The Royal Society of Chemistry

4.
H. F. T. Klare and M. Oestreich*,
Silylium ions in catalysis (Perspective),
(Special Issue "New Horizon of Organosilicon Chemistry"),
Dalton Trans. 2010, 39, 9176-9184. (Abstract)

© 2009 WILEY-VCH

3.
H. F. T. Klare, K. Bergander, and M. Oestreich*,
Taming the Silylium Ion for Low-Temperature Diels–Alder Reactions,
Angew. Chem. 2009, 121, 9241-9243;
Angew. Chem. Int. Ed. 2009, 48, 9077-9079. (Abstract)
Highlighted in Nachr. Chem. 2010, 58, 7.
Highlighted in Angew. Chem. Int. Ed. 2012, 51, 4526-4528.

© 2009 WILEY-VCH

2.
H. F. T. Klare and M. Oestreich*,
Asymmetric Ring-Closing Metathesis with a Twist (Highlight),
Angew. Chem. 2009, 121, 2119-2123;
Angew. Chem. Int. Ed. 2009, 48, 2085-2089. (Abstract)

© 2007 WILEY-VCH

1.
H. F. T. Klare and M. Oestreich*,
Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols,
Angew. Chem. 2007, 119, 9496-9499;
Angew. Chem. Int. Ed. 2007, 46, 9335-9338. (Abstract)