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Lupe [1]

Dr. Hendrik F. T. Klare


Institut für Chemie
Sekr. C3
Straße des 17. Juni 115
10623 Berlin, Germany


fon: +49 30 314 29909
fax: +49 30 314 75804

email: hendrik.klare(at)tu-berlin.de [2]

Research Gate [3]

ORCID
[4]

Academic Career
  • Senior Scientist/Lecturer with Professor Martin Oestreich at the Technische Universität Berlin, Germany (January 2013 present)
  • Postdoc with Professor Brian M. Stoltz at the California Institute of Technology, Pasadena, USA (December 2011 December 2012)
    "Oxidative Coupling of Oxindoles with Nucleophiles"
  • Research Stay with Professor Gerhard Erker at the Westfälische Wilhelms-Universität Münster, Germany (September 2011 November 2011)
    "SiH Bond Activation with Frustrated Lewis Pairs"
  • Ph.D. with Professor Martin Oestreich at the Westfälische Wilhelms-Universität Münster, Germany (April 2007 May 2011)
    "Generation of Stabilized Silylium Ions for Catalysis"
  • Research Stay with Professor Kazuyuki Tatsumi at Nagoya University, Japan (September 2009 March 2010)
    "Cooperative SiH Bond Activation with Transition Metal Thiolate Complexes"
  • Diploma with Professor Martin Oestreich at the Westfälische Wilhelms-Universität Münster, Germany (October 2006 March 2007)
    "Rhodium-Catalyzed Dehydrogenative SiO Coupling: Chiral Recognition with Silicon-Stereogenic Silanes"
  • Studies in Chemistry at the Westfälische Wilhelms-Universität Münster, Germany (October 2001 March 2007)
Scholarships
  • Postdoctoral Research Fellowship of the German Academic Exchange Service (DAAD) (December 2011 November 2012)
  • Predoctoral Fellowship of the International Research Training Group (IRTG) Münster–Nagoya "Complex Functional Systems in Chemistry: Design, Development and Applications", GRK 1143 of the Deutsche Forschungsgemeinschaft (DFG) (April 2007 March 2010)

Publications

Lupe [5]

26.
J. Fuchs, H. F. T. Klare, and M. Oestreich*,
Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst,
ACS Catal. 2017, 7, 8338-8342 [6]. (Abstract [7])

Lupe [8]

25.
H. F. T. Klare*,
Catalytic C–H Arylation of Unactivated C–H Bonds by Silylium Ion-Promoted C(sp2)–F Bond Activation (Perspective),
ACS Catal. 2017, 7, 6999-7002 [9]. (Abstract [10])

Lupe [11]

24.
L. Omann, C. D. F. Königs, H. F. T. Klare,* and M. Oestreich*,
Cooperative Catalysis at MetalSulfur Bonds (Account),
Acc. Chem. Res. 2017, 50, 1258-1269 [12]. (Abstract [13])

Lupe [14]

23.
W.-B. Liu, D. P. Schuman, Y.-F. Yang, A. A. Toutov, Y. Liang, H. F. T. Klare, N. Nesnas, M. Oestreich, D. G. Blackmond, S. C. Virgil, S. Banerjee, R. N. Zare, R. H. Grubbs, K. N. Houk,* and B. M. Stoltz*,
Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study,
J. Am. Chem. Soc. 2017, 139, 6867-6879 [15]. (Abstract [16])

Lupe [17]

22.
H. F. T. Klare, A. F. G. Goldberg, D. C. Duquette, and B. M. Stoltz*,
Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives,
Org. Lett. 2017, 19, 988-991 [18]. (Abstract [19])

Lupe [20]

21.
Q. Yin, H. F. T. Klare,* and M. Oestreich*,
Catalytic Friedel–Crafts C–H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes,
Angew. Chem. 2017, 129, 3766-3771;
Angew. Chem. Int. Ed. 2017, 56, 3712-3717 [21]. (Abstract [22])
Highlighted in SYNFACTS 2017, 13, 529 [23].

Lupe [24]

20.
H. F. T. Klare and M. Oestreich*,
Teaching nature the unnatural (Perspective),
Science 2016, 354, 970 [25]. (Abstract [26])

Lupe [27]

19.
Q. Yin, S. Kemper, H. F. T. Klare,* and M. Oestreich*,
Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6F5)3 Cannot Do!,
Chem. Eur. J. 2016, 22, 13840-13844 [28]. (Abstract [29])

Lupe [30]

18.
Q.-A. Chen, H. F. T. Klare, and M. Oestreich*,
Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation,
J. Am. Chem. Soc. 2016, 138, 7868-7871 [31]. (Abstract [32])
ACS AuthorChoice (open access)

Lupe [33]

17.
R. K. Schmidt, H. F. T. Klare, R. Fröhlich, and M. Oestreich*,
Planar Chiral, Ferrocene-Stabilized Silicon Cations,
Chem. Eur. J. 2016, 22, 5376-5383 [34]. (Abstract [35])

Lupe [36]

16.
Q. Yin, H. F. T. Klare, and M. Oestreich*,
FriedelCrafts-Type Intermolecular CH Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts,
Angew. Chem. 2016, 128, 3256-3260;
Angew. Chem. Int. Ed. 2016, 55, 3204-3207 [37]. (Abstract [38])

Lupe [39]

15.
T. Stahl, P. Hrobárik,* C. D. F. Königs, Y. Ohki, K. Tatsumi, S. Kemper, M. Kaupp, H. F. T. Klare,* and M. Oestreich*,
Mechanism of the cooperative SiH bond activation at RuS bonds,
Chem. Sci. 2015, 6, 4324-4334 [40]. (Abstract)
(open access)

Lupe [41]

14.
V. H. G. Rohde, P. Pommerening, H. F. T. Klare, and M. Oestreich*,
Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts,
Organometallics 2014, 33, 3618-3628 [42]. (Abstract [43])

Lupe [44]

13.
T. T. Metsänen, P. Hrobárik,* H. F. T. Klare, M. Kaupp, and M. Oestreich*,
Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart's Cationic Iridium(III) Pincer Complex,
J. Am. Chem. Soc. 2014, 136, 6912-6915 [45]. (Abstract [46])
Highlighted in ChemCatChem 2014, 6, 2486-2489 [47].

Lupe [48]

12.
J. Hermeke, H. F. T. Klare, and M. Oestreich*,
Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative Si–N Coupling
(ISOS XVII Conference Issue New Frontiers and Challenges in Silicon Chemistry [49]),
Chem. Eur. J. 2014, 20, 9250-9254 [50]. (Abstract [51])

Lupe [52]

11.
C. D. F. Königs, H. F. T. Klare, and M. Oestreich*,
Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners,
Angew. Chem. 2013, 125, 10260-10263;
Angew. Chem. Int. Ed. 2013, 52, 10076-10079 [53]. (Abstract [54])
Selected as a "Hot Paper" by Angewandte Chemie.

Lupe [55]

10.
T. Stahl, H. F. T. Klare,* and M. Oestreich*,
Main-Group Lewis Acids for C–F Bond Activation (Perspective),
ACS Catal. 2013, 3, 1578-1587 [56]. (Abstract [57])
Featured on the Cover of ACS Catalysis [58].

Lupe [59]

9.
C. D. F. Königs, M. F. Müller, N. Aiguabella, H. F. T. Klare, and M. Oestreich*,
Catalytic dehydrogenative SiN coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base,
Chem. Commun. 2013, 49, 1506-1508 [60]. (Abstract [61])

Lupe [62]

8.
T. Stahl, H. F. T. Klare, and M. Oestreich*,
C(sp3)F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged RuS Dimer in the Catalytic Cycle,
J. Am. Chem. Soc. 2013, 135, 1248-1251 [63]. (Abstract [64])

Lupe [65]

7.
W. Nie, H. F. T. Klare, M. Oestreich, R. Fröhlich, G. Kehr, and G. Erker*,
Reversible Heterolytic SiH Bond Activation by an Intramolecular Frustrated Lewis Pair
(Special Issue dedicated to Professor Heribert Offermanns),
Z. Naturforsch. 2012, 67b, 987-994 [66]. (Abstract [67])

Lupe [68]

6.
C. D. F. Königs, H. F. T. Klare, Y. Ohki,* K. Tatsumi,* and M. Oestreich*,
Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes,
Org. Lett. 2012, 14, 2842-2845 [69]. (Abstract [70])
Included into Organic Chemistry Highlights under www.organic-chemistry.org [71].

Lupe [72]

5.
H. F. T. Klare, M. Oestreich,* J.-i. Ito, H. Nishiyama, Y. Ohki,* and K. Tatsumi*,
Cooperative Catalytic Activation of SiH Bonds by a Polar RuS Bond: Regioselective Low-Temperature CH Silylation of Indoles under Neutral Conditions by a FriedelCrafts Mechanism,
J. Am. Chem. Soc. 2011, 133, 3312-3315 [73]. (Abstract [74])

Lupe [75]

4.
H. F. T. Klare and M. Oestreich*,
Silylium ions in catalysis (Perspective),
(Special Issue "New Horizon of Organosilicon Chemistry"),
Dalton Trans. 2010, 39, 9176-9184 [76]. (Abstract [77])

Lupe [78]

3.
H. F. T. Klare, K. Bergander, and M. Oestreich*,
Taming the Silylium Ion for Low-Temperature DielsAlder Reactions,
Angew. Chem. 2009, 121, 9241-9243;
Angew. Chem. Int. Ed. 2009, 48, 9077-9079 [79]. (Abstract [80])
Highlighted in Nachr. Chem. 2010, 58, 7 [81].
Highlighted in Angew. Chem. Int. Ed. 2012, 51, 4526-4528 [82].

Lupe [83]

2.
H. F. T. Klare and M. Oestreich*,
Asymmetric Ring-Closing Metathesis with a Twist (Highlight),
Angew. Chem. 2009, 121, 2119-2123;
Angew. Chem. Int. Ed. 2009, 48, 2085-2089 [84]. (Abstract [85])

Lupe [86]

1.
H. F. T. Klare and M. Oestreich*,
Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols,
Angew. Chem. 2007, 119, 9496-9499;
Angew. Chem. Int. Ed. 2007, 46, 9335-9338 [87]. (Abstract [88])

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